Literature DB >> 21556439

Active thionium species mediated functionalization at the 2α-position of indole derivatives.

Kazuhiro Higuchi1, Masanori Tayu, Tomomi Kawasaki.   

Abstract

A combination of dimethyl sulfoxide (DMSO) and trifluoroacetic anhydride (TFAA) mediates functionalization at the 2α-position of indole derivatives. Carbon and heteroatom nucleophiles were directly introduced via a one-pot procedure in excellent yields. This journal is © The Royal Society of Chemistry 2011

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Year:  2011        PMID: 21556439     DOI: 10.1039/c1cc11645b

Source DB:  PubMed          Journal:  Chem Commun (Camb)        ISSN: 1359-7345            Impact factor:   6.222


  4 in total

1.  Cu-Catalyzed Oxidation of C2 and C3 Alkyl-Substituted Indole via Acyl Nitroso Reagents.

Authors:  Jun Zhang; Saeedeh Torabi Kohlbouni; Babak Borhan
Journal:  Org Lett       Date:  2018-12-21       Impact factor: 6.005

2.  Development of an alkaloid-pyrone annulation: synthesis of pleiomaltinine.

Authors:  Robert E Ziegler; Shin-Jowl Tan; Toh-Seok Kam; John A Porco
Journal:  Angew Chem Int Ed Engl       Date:  2012-08-15       Impact factor: 15.336

3.  Bond-Forming and -Breaking Reactions at Sulfur(IV): Sulfoxides, Sulfonium Salts, Sulfur Ylides, and Sulfinate Salts.

Authors:  Daniel Kaiser; Immo Klose; Rik Oost; James Neuhaus; Nuno Maulide
Journal:  Chem Rev       Date:  2019-06-25       Impact factor: 60.622

4.  High Site Selectivity in Electrophilic Aromatic Substitutions: Mechanism of C-H Thianthrenation.

Authors:  Fabio Juliá; Qianzhen Shao; Meng Duan; Matthew B Plutschack; Florian Berger; Javier Mateos; Chenxi Lu; Xiao-Song Xue; K N Houk; Tobias Ritter
Journal:  J Am Chem Soc       Date:  2021-09-21       Impact factor: 15.419

  4 in total

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