| Literature DB >> 21542601 |
Kazumi Okuro1, Joanna Gurnham, Howard Alper.
Abstract
Ionic diamine rhodium complex (1) catalyzes the reductive N-cyclization of 2-vinylnitroarenes using carbon monoxide as a reducing agent to afford functionalized indoles. The catalytic system allows direct access to indoles with ester and ketone groups at the 2- or 3-position, in good yields.Entities:
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Year: 2011 PMID： 21542601 DOI： 10.1021/jo200320k
Source DB: PubMed Journal: J Org Chem ISSN： 0022-3263 Impact factor: 4.354