| Literature DB >> 21528847 |
Abstract
An efficient, highly diastereoselective method for the preparation of protected cis-2-aminocyclopropanols from N-tert-butanesulfinyl ketimines and various aryl acylsilanes is described. A tandem process for carbon-carbon bond formation via nucleophilic addition to acylsilanes, Brook rearrangement, and intramolecular Mannich reaction has been developed.Entities:
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Year: 2011 PMID： 21528847 DOI： 10.1021/jo200585r
Source DB: PubMed Journal: J Org Chem ISSN： 0022-3263 Impact factor: 4.354