| Literature DB >> 21522930 |
Benjamin F Wicker1, Rachel Seaman, Norris W Hoffman, James H Davis, Richard E Sykora.
Abstract
The title acesulfamate complex, [Pd(C(30)H(22)FO(2)P(2))(C(4)H(4)NO(4)S)], contains a four-coordinate Pd(II) ion with the expected, although relatively distorted, square-planar geometry where the four L-Pd-L angles range from 79.58 (8) to 102.47 (7)°. The acesulfamate ligand is N-bound to Pd [Pd-N = 2.127 (2) Å] with a dihedral angle of 76.35 (6)° relative to the square plane. Relatively long phen-yl-acesulfamate C-H⋯O and phen-yl-fluorine C-H⋯F inter-actions consolidate the crystal packing.Entities:
Year: 2011 PMID: 21522930 PMCID: PMC3051636 DOI: 10.1107/S1600536811002911
Source DB: PubMed Journal: Acta Crystallogr Sect E Struct Rep Online ISSN: 1600-5368