Literature DB >> 21522523

Poly[[μ(2)-(1Z,N'E)-2-(1,3-benzothia-zol-2-ylsulfan-yl)-N'-(2-oxidobenzyl-idene-κO:O)acetohydrazidato-κO,N'](pyridine-κN)copper(II)].

Vladimir V Bon1, Svitlana I Orysyk, Vasily I Pekhnyo.   

Abstract

In the title compound, [Cu(C(16)H(11)N(3)O(2)S(2))(C(5)H(5)N)](n), the Cu(II) atom displays a square-pyramidal CuN(2)O(3) coordination geometry with strong elongation in the vertex direction. The hydrazone mol-ecule is coordinated to the Cu(II) atom in a tridentate manner in the enolic form, creating five- and six-membered chelate metallarings. The pyridine mol-ecule completes the square-planar base of the copper coordination environment. The crystal structure displays zigzag polymeric Cu-O-Cu chains along [001]. Several weak π-π inter-actions between benzothia-zole rings were found in the same direction [centroid-centroid distances = 3.7484 (16), 3.7483 (16), 3.6731 (17) and 3.7649 (17) Å].

Entities:  

Year:  2010        PMID: 21522523      PMCID: PMC3050211          DOI: 10.1107/S160053681004986X

Source DB:  PubMed          Journal:  Acta Crystallogr Sect E Struct Rep Online        ISSN: 1600-5368


  3 in total

1.  Synthesis and antioxidant activity evaluation of a syringic hydrazones family.

Authors:  Nadji Belkheiri; Benaissa Bouguerne; Florence Bedos-Belval; Hubert Duran; Corinne Bernis; Robert Salvayre; Anne Nègre-Salvayre; Michel Baltas
Journal:  Eur J Med Chem       Date:  2010-03-25       Impact factor: 6.514

2.  A short history of SHELX.

Authors:  George M Sheldrick
Journal:  Acta Crystallogr A       Date:  2007-12-21       Impact factor: 2.290

3.  Thiosemicarbazones, semicarbazones, dithiocarbazates and hydrazide/hydrazones: anti-Mycobacterium tuberculosis activity and cytotoxicity.

Authors:  Fernando R Pavan; Pedro I da S Maia; Sergio R A Leite; Victor M Deflon; Alzir A Batista; Daisy N Sato; Scott G Franzblau; Clarice Q F Leite
Journal:  Eur J Med Chem       Date:  2010-01-28       Impact factor: 6.514

  3 in total

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