Acetonitrile-[2-({bis[2,4,6-tris-(trifluorido-meth-yl)phen-yl]phosphan-yloxy}meth-yl)pyridine]-meth-ylpalladium(II) hexa-fluoro-anti-monate dichloro-methane hemisolvate.

In the title compound, [Pd(CH(3))(C(24)H(10)F(18)NOP)(CH(3)CN)][SbF(6)]·0.5CH(2)Cl(2), the Pd(II) atom has a distorted square-planar environment being coordinated by an acetonitrile N atom [Pd-N = 2.079 (3) Å], a methyl C atom [Pd-C = 2.047 (4) Å] and the bidentate ligand 2-({[2,4,6-tris-(trifluoro-meth-yl)phen-yl]phosphan-yloxy}meth-yl)pyridine (L). In L, the short distance of 3.621 (3) Å between the centroids of pyridine and benzene rings indicates the presence of a π-π inter-action. The crystal packing exhibits weak inter-molecular C-H⋯F contacts. The solvent mol-ecule has been treated as disordered between two positions of equal occupancy related by an inversion center.

Related literature

For related compounds, see: Li et al. (2011 ▶) and references therein. Di[tris­(trifluoro­meth­yl)phen­yl]phosphine chloride was prepared according to Batsanov et al. (2002 ▶).

Experimental

Crystal data

[Pd(CH3)(C24H10F18NOP)(C2H3N)][SbF6]·0.5CH2Cl2

M = 1142.00

Triclinic,

a = 8.6993 (4) Å

b = 11.8120 (5) Å

c = 18.1494 (8) Å

α = 78.557 (2)°

β = 82.007 (2)°

γ = 79.526 (2)°

V = 1787.14 (14) Å3

Z = 2

Cu Kα radiation

μ = 12.64 mm−1

T = 100 K

0.38 × 0.13 × 0.11 mm

Data collection

Bruker APEXII CCD diffractometer

Absorption correction: numerical (SADABS; Bruker, 2007 ▶) T min = 0.086, T max = 0.348

19130 measured reflections

6422 independent reflections

5830 reflections with I > 2σ(I)

R int = 0.035

Refinement

R[F 2 > 2σ(F 2)] = 0.036

wR(F 2) = 0.093

S = 1.05

6422 reflections

534 parameters

3 restraints

H-atom parameters constrained

Δρmax = 1.46 e Å−3

Δρmin = −0.88 e Å−3

Data collection: APEX2 (Bruker, 2007 ▶); cell refinement: SAINT (Bruker, 2007 ▶); data reduction: SAINT; program(s) used to solve structure: SHELXS97 (Sheldrick, 2008 ▶); program(s) used to refine structure: SHELXL97 (Sheldrick, 2008 ▶); molecular graphics: SHELXTL (Sheldrick, 2008 ▶); software used to prepare material for publication: SHELXTL.

Crystal structure: contains datablocks I, global. DOI: 10.1107/S1600536811005757/cv5046sup1.cif

Structure factors: contains datablocks I. DOI: 10.1107/S1600536811005757/cv5046Isup2.hkl

Additional supplementary materials: crystallographic information; 3D view; checkCIF report

[Pd(CH3)(C24H10F18NOP)(C2H3N)][SbF6]·0.5CH2Cl2	Z = 2
Mr = 1142.00	F(000) = 1098
Triclinic, P1	Dx = 2.122 Mg m−3
Hall symbol: -P 1	Cu Kα radiation, λ = 1.54178 Å
a = 8.6993 (4) Å	Cell parameters from 8055 reflections
b = 11.8120 (5) Å	θ = 2.5–69.1°
c = 18.1494 (8) Å	µ = 12.64 mm−1
α = 78.557 (2)°	T = 100 K
β = 82.007 (2)°	Block, colourless
γ = 79.526 (2)°	0.38 × 0.13 × 0.11 mm
V = 1787.14 (14) Å3

Bruker APEXII CCD diffractometer	6422 independent reflections
Radiation source: fine-focus sealed tube	5830 reflections with I > 2σ(I)
graphite	Rint = 0.035
φ and ω scans	θmax = 69.7°, θmin = 2.5°
Absorption correction: numerical (SAINT; Bruker, 2007)	h = −10→10
Tmin = 0.086, Tmax = 0.348	k = −14→14
19130 measured reflections	l = −21→21

Refinement on F2	Primary atom site location: structure-invariant direct methods
Least-squares matrix: full	Secondary atom site location: difference Fourier map
R[F2 > 2σ(F2)] = 0.036	Hydrogen site location: inferred from neighbouring sites
wR(F2) = 0.093	H-atom parameters constrained
S = 1.05	w = 1/[σ2(Fo2) + (0.0539P)2 + 2.2192P] where P = (Fo2 + 2Fc2)/3
6422 reflections	(Δ/σ)max = 0.043
534 parameters	Δρmax = 1.46 e Å−3
3 restraints	Δρmin = −0.88 e Å−3

Geometry. All e.s.d.'s (except the e.s.d. in the dihedral angle between two l.s. planes) are estimated using the full covariance matrix. The cell e.s.d.'s are taken into account individually in the estimation of e.s.d.'s in distances, angles and torsion angles; correlations between e.s.d.'s in cell parameters are only used when they are defined by crystal symmetry. An approximate (isotropic) treatment of cell e.s.d.'s is used for estimating e.s.d.'s involving l.s. planes.

Refinement. Refinement of F2 against ALL reflections. The weighted R-factor wR and goodness of fit S are based on F2, conventional R-factors R are based on F, with F set to zero for negative F2. The threshold expression of F2 > σ(F2) is used only for calculating R-factors(gt) etc. and is not relevant to the choice of reflections for refinement. R-factors based on F2 are statistically about twice as large as those based on F, and R- factors based on ALL data will be even larger.

	x	y	z	Uiso*/Ueq	Occ. (<1)
Pd1	0.88403 (6)	0.79572 (4)	0.19133 (3)	0.02224 (17)
P1	0.7299 (2)	0.67699 (15)	0.26210 (10)	0.0200 (4)
C1	0.8178 (10)	0.9157 (7)	0.2617 (5)	0.0305 (17)
H1A	0.9104	0.9464	0.2697	0.046*
H1B	0.7698	0.8781	0.3103	0.046*
H1C	0.7415	0.9801	0.2387	0.046*
N2	1.0136 (8)	0.9151 (6)	0.1220 (4)	0.0279 (14)
C3	1.0826 (9)	0.9841 (7)	0.0885 (4)	0.0251 (15)
C4	1.1735 (10)	1.0729 (7)	0.0447 (5)	0.0316 (17)
H4A	1.1014	1.1415	0.0232	0.047*
H4B	1.2423	1.0406	0.0039	0.047*
H4C	1.2374	1.0960	0.0780	0.047*
N5	0.9618 (7)	0.6603 (6)	0.1231 (3)	0.0251 (13)
C6	1.1173 (9)	0.6238 (7)	0.1095 (4)	0.0283 (16)
H6	1.1877	0.6752	0.1122	0.034*
C7	1.1789 (10)	0.5154 (8)	0.0918 (4)	0.0318 (17)
H7	1.2893	0.4931	0.0820	0.038*
C8	1.0768 (10)	0.4392 (8)	0.0886 (5)	0.0322 (17)
H8	1.1161	0.3626	0.0788	0.039*
C9	0.9161 (10)	0.4774 (7)	0.0999 (4)	0.0295 (16)
H9	0.8441	0.4278	0.0962	0.035*
C10	0.8615 (9)	0.5875 (7)	0.1165 (4)	0.0253 (15)
C11	0.6888 (9)	0.6356 (7)	0.1274 (4)	0.0266 (16)
H11A	0.6704	0.7160	0.0980	0.032*
H11B	0.6292	0.5872	0.1068	0.032*
O12	0.6279 (6)	0.6381 (4)	0.2067 (3)	0.0228 (10)
C13	0.5605 (8)	0.7290 (6)	0.3291 (4)	0.0207 (14)
C14	0.4259 (9)	0.7999 (6)	0.2991 (4)	0.0225 (14)
C15	0.2888 (9)	0.8282 (6)	0.3458 (4)	0.0255 (15)
H15	0.1999	0.8755	0.3243	0.031*
C16	0.2801 (9)	0.7889 (7)	0.4226 (4)	0.0272 (16)
C17	0.4112 (9)	0.7274 (6)	0.4540 (4)	0.0259 (15)
H17	0.4076	0.7050	0.5074	0.031*
C18	0.5494 (9)	0.6975 (6)	0.4090 (4)	0.0243 (15)
C19	0.4112 (9)	0.8531 (7)	0.2163 (4)	0.0259 (15)
F20	0.3435 (5)	0.7874 (4)	0.1823 (2)	0.0305 (10)
F21	0.5456 (5)	0.8716 (4)	0.1750 (2)	0.0297 (10)
F22	0.3187 (6)	0.9577 (4)	0.2110 (3)	0.0355 (11)
C23	0.1304 (10)	0.8149 (8)	0.4732 (5)	0.0348 (18)
F24	0.0112 (6)	0.8704 (6)	0.4348 (3)	0.0530 (15)
F25	0.1458 (8)	0.8773 (8)	0.5225 (5)	0.084 (3)
F26	0.0838 (7)	0.7169 (6)	0.5117 (4)	0.0626 (18)
C27	0.6838 (10)	0.6287 (7)	0.4516 (4)	0.0306 (17)
F28	0.6692 (6)	0.6487 (5)	0.5223 (3)	0.0436 (13)
F29	0.6908 (6)	0.5127 (4)	0.4572 (3)	0.0388 (11)
F30	0.8222 (5)	0.6545 (4)	0.4194 (3)	0.0348 (10)
C31	0.8327 (8)	0.5257 (6)	0.2986 (4)	0.0207 (14)
C32	0.7605 (9)	0.4264 (7)	0.2976 (4)	0.0260 (15)
C33	0.8487 (10)	0.3176 (7)	0.2930 (5)	0.0304 (17)
H33	0.7981	0.2540	0.2903	0.036*
C34	1.0100 (10)	0.3012 (7)	0.2922 (5)	0.0338 (19)
C35	1.0823 (9)	0.3903 (7)	0.3014 (5)	0.0318 (17)
H35	1.1921	0.3765	0.3054	0.038*
C36	0.9955 (9)	0.5019 (7)	0.3047 (4)	0.0263 (15)
C37	0.5854 (9)	0.4261 (7)	0.3027 (4)	0.0275 (16)
F38	0.4982 (5)	0.5129 (4)	0.3348 (2)	0.0268 (9)
F39	0.5506 (6)	0.3264 (4)	0.3475 (3)	0.0340 (10)
F40	0.5333 (5)	0.4294 (4)	0.2367 (3)	0.0334 (10)
C41	1.1054 (12)	0.1834 (8)	0.2817 (6)	0.047 (2)
F42	1.0618 (9)	0.0980 (5)	0.3320 (4)	0.076 (2)
F43	1.0811 (9)	0.1564 (6)	0.2159 (4)	0.074 (2)
F44	1.2567 (7)	0.1820 (6)	0.2777 (5)	0.076 (2)
C45	1.1009 (9)	0.5837 (7)	0.3185 (5)	0.0292 (16)
F46	1.1596 (5)	0.5423 (4)	0.3843 (3)	0.0351 (11)
F47	1.2226 (5)	0.5887 (5)	0.2645 (3)	0.0364 (11)
F48	1.0343 (5)	0.6941 (4)	0.3209 (3)	0.0317 (10)
Sb1	0.60710 (6)	0.23126 (4)	0.07962 (3)	0.02735 (18)
F11	0.5822 (6)	0.3936 (4)	0.0756 (3)	0.0385 (11)
F12	0.6312 (8)	0.2064 (5)	0.1830 (3)	0.0544 (15)
F13	0.6346 (8)	0.0698 (5)	0.0829 (4)	0.0577 (17)
F14	0.5886 (7)	0.2566 (6)	−0.0242 (3)	0.0483 (14)
F15	0.8255 (6)	0.2283 (5)	0.0575 (3)	0.0467 (13)
F16	0.3891 (6)	0.2383 (5)	0.0997 (4)	0.0528 (15)
Cl1	0.5356 (9)	0.0251 (5)	0.4168 (5)	0.153 (3)
C50	0.390 (4)	0.059 (2)	0.481 (2)	0.106 (13)	0.50
H50A	0.2931	0.0323	0.4729	0.127*	0.50
H50B	0.3670	0.1448	0.4795	0.127*	0.50

	U11	U22	U33	U12	U13	U23
Pd1	0.0200 (3)	0.0197 (3)	0.0254 (3)	−0.0038 (2)	−0.0024 (2)	0.0004 (2)
P1	0.0169 (8)	0.0179 (8)	0.0230 (8)	−0.0007 (6)	−0.0016 (6)	−0.0008 (7)
C1	0.035 (4)	0.022 (4)	0.035 (4)	−0.004 (3)	−0.006 (3)	−0.004 (3)
N2	0.025 (3)	0.027 (3)	0.030 (3)	−0.006 (3)	−0.003 (3)	0.000 (3)
C3	0.023 (4)	0.025 (4)	0.027 (4)	−0.002 (3)	−0.004 (3)	−0.004 (3)
C4	0.033 (4)	0.028 (4)	0.033 (4)	−0.011 (3)	0.000 (3)	0.000 (3)
N5	0.025 (3)	0.025 (3)	0.023 (3)	−0.005 (3)	0.001 (2)	0.000 (3)
C6	0.024 (4)	0.033 (4)	0.026 (4)	−0.006 (3)	0.003 (3)	−0.001 (3)
C7	0.023 (4)	0.039 (5)	0.029 (4)	−0.003 (3)	0.005 (3)	−0.003 (3)
C8	0.034 (4)	0.030 (4)	0.030 (4)	0.000 (3)	0.002 (3)	−0.007 (3)
C9	0.030 (4)	0.033 (4)	0.026 (4)	−0.008 (3)	0.003 (3)	−0.007 (3)
C10	0.026 (4)	0.030 (4)	0.020 (3)	−0.007 (3)	0.002 (3)	−0.004 (3)
C11	0.024 (4)	0.034 (4)	0.021 (3)	−0.006 (3)	−0.002 (3)	−0.002 (3)
O12	0.018 (2)	0.025 (3)	0.024 (2)	−0.003 (2)	−0.0003 (19)	−0.004 (2)
C13	0.017 (3)	0.016 (3)	0.027 (3)	−0.001 (3)	−0.001 (3)	−0.003 (3)
C14	0.024 (4)	0.015 (3)	0.029 (4)	−0.003 (3)	−0.006 (3)	−0.003 (3)
C15	0.024 (4)	0.019 (4)	0.033 (4)	0.000 (3)	−0.006 (3)	−0.005 (3)
C16	0.028 (4)	0.020 (4)	0.034 (4)	−0.004 (3)	0.003 (3)	−0.010 (3)
C17	0.033 (4)	0.019 (4)	0.025 (3)	−0.003 (3)	−0.002 (3)	−0.003 (3)
C18	0.025 (4)	0.020 (4)	0.028 (4)	−0.003 (3)	−0.003 (3)	−0.004 (3)
C19	0.023 (4)	0.024 (4)	0.028 (4)	0.001 (3)	−0.003 (3)	−0.003 (3)
F20	0.028 (2)	0.036 (3)	0.028 (2)	−0.0051 (19)	−0.0070 (18)	−0.0070 (19)
F21	0.025 (2)	0.029 (2)	0.030 (2)	−0.0036 (18)	−0.0027 (18)	0.0046 (19)
F22	0.038 (3)	0.028 (2)	0.035 (2)	0.011 (2)	−0.007 (2)	−0.002 (2)
C23	0.027 (4)	0.039 (5)	0.035 (4)	0.003 (4)	0.001 (3)	−0.008 (4)
F24	0.029 (3)	0.067 (4)	0.046 (3)	0.014 (3)	0.006 (2)	0.001 (3)
F25	0.046 (4)	0.136 (7)	0.091 (5)	−0.017 (4)	0.020 (4)	−0.085 (6)
F26	0.043 (3)	0.057 (4)	0.065 (4)	0.003 (3)	0.024 (3)	0.012 (3)
C27	0.032 (4)	0.028 (4)	0.026 (4)	0.005 (3)	−0.004 (3)	0.000 (3)
F28	0.043 (3)	0.057 (3)	0.026 (2)	0.013 (2)	−0.010 (2)	−0.008 (2)
F29	0.039 (3)	0.028 (2)	0.040 (3)	0.006 (2)	−0.004 (2)	0.006 (2)
F30	0.025 (2)	0.043 (3)	0.036 (2)	−0.002 (2)	−0.0054 (19)	−0.006 (2)
C31	0.018 (3)	0.019 (3)	0.021 (3)	0.000 (3)	0.002 (3)	0.001 (3)
C32	0.022 (4)	0.025 (4)	0.027 (4)	−0.003 (3)	0.005 (3)	−0.002 (3)
C33	0.030 (4)	0.023 (4)	0.034 (4)	−0.004 (3)	0.010 (3)	−0.002 (3)
C34	0.027 (4)	0.024 (4)	0.042 (5)	0.003 (3)	0.011 (3)	0.000 (4)
C35	0.020 (4)	0.028 (4)	0.039 (4)	0.002 (3)	0.004 (3)	0.004 (3)
C36	0.023 (4)	0.025 (4)	0.027 (4)	−0.001 (3)	0.001 (3)	0.001 (3)
C37	0.026 (4)	0.022 (4)	0.034 (4)	−0.005 (3)	0.004 (3)	−0.006 (3)
F38	0.019 (2)	0.025 (2)	0.035 (2)	−0.0022 (17)	0.0041 (17)	−0.0083 (19)
F39	0.030 (2)	0.025 (2)	0.044 (3)	−0.0108 (19)	0.010 (2)	−0.004 (2)
F40	0.031 (2)	0.037 (3)	0.035 (2)	−0.010 (2)	−0.0001 (19)	−0.012 (2)
C41	0.037 (5)	0.028 (5)	0.062 (6)	0.007 (4)	0.020 (4)	−0.005 (4)
F42	0.086 (5)	0.026 (3)	0.089 (5)	0.013 (3)	0.036 (4)	0.006 (3)
F43	0.087 (5)	0.050 (4)	0.076 (5)	0.019 (4)	0.004 (4)	−0.028 (4)
F44	0.034 (3)	0.043 (3)	0.148 (8)	0.012 (3)	0.005 (4)	−0.033 (4)
C45	0.019 (4)	0.031 (4)	0.032 (4)	−0.002 (3)	−0.003 (3)	0.005 (3)
F46	0.029 (2)	0.040 (3)	0.033 (2)	−0.002 (2)	−0.0103 (19)	0.004 (2)
F47	0.023 (2)	0.048 (3)	0.037 (3)	−0.012 (2)	0.0014 (19)	−0.002 (2)
F48	0.026 (2)	0.025 (2)	0.043 (3)	−0.0037 (18)	−0.0132 (19)	0.002 (2)
Sb1	0.0290 (3)	0.0234 (3)	0.0279 (3)	−0.0051 (2)	0.0026 (2)	−0.0033 (2)
F11	0.035 (3)	0.024 (2)	0.056 (3)	−0.004 (2)	−0.004 (2)	−0.005 (2)
F12	0.083 (4)	0.045 (3)	0.028 (3)	0.007 (3)	−0.006 (3)	−0.004 (2)
F13	0.083 (5)	0.024 (3)	0.063 (4)	−0.013 (3)	0.017 (3)	−0.013 (3)
F14	0.050 (3)	0.068 (4)	0.030 (3)	−0.013 (3)	−0.007 (2)	−0.010 (3)
F15	0.025 (3)	0.049 (3)	0.060 (3)	0.001 (2)	−0.001 (2)	−0.004 (3)
F16	0.029 (3)	0.055 (3)	0.074 (4)	−0.018 (3)	0.015 (3)	−0.018 (3)
Cl1	0.147 (5)	0.104 (4)	0.221 (8)	−0.059 (4)	−0.011 (5)	−0.035 (5)
C50	0.09 (2)	0.044 (14)	0.19 (4)	−0.035 (15)	0.02 (2)	−0.05 (2)

Pd1—C1	2.047 (8)	C19—F21	1.327 (9)
Pd1—N2	2.079 (7)	C19—F20	1.336 (9)
Pd1—N5	2.170 (6)	C19—F22	1.340 (9)
Pd1—P1	2.2146 (18)	C23—F25	1.301 (11)
P1—O12	1.609 (5)	C23—F26	1.328 (11)
P1—C13	1.870 (7)	C23—F24	1.328 (10)
P1—C31	1.883 (7)	C27—F30	1.324 (10)
C1—H1A	0.9800	C27—F28	1.335 (9)
C1—H1B	0.9800	C27—F29	1.344 (10)
C1—H1C	0.9800	C31—C36	1.408 (11)
N2—C3	1.128 (10)	C31—C32	1.432 (10)
C3—C4	1.467 (11)	C32—C33	1.383 (11)
C4—H4A	0.9800	C32—C37	1.513 (11)
C4—H4B	0.9800	C33—C34	1.379 (12)
C4—H4C	0.9800	C33—H33	0.9500
N5—C6	1.347 (10)	C34—C35	1.367 (12)
N5—C10	1.363 (10)	C34—C41	1.517 (11)
C6—C7	1.377 (12)	C35—C36	1.403 (11)
C6—H6	0.9500	C35—H35	0.9500
C7—C8	1.388 (12)	C36—C45	1.523 (11)
C7—H7	0.9500	C37—F40	1.329 (9)
C8—C9	1.388 (12)	C37—F38	1.341 (9)
C8—H8	0.9500	C37—F39	1.349 (9)
C9—C10	1.378 (11)	C41—F42	1.294 (11)
C9—H9	0.9500	C41—F44	1.305 (12)
C10—C11	1.507 (11)	C41—F43	1.347 (14)
C11—O12	1.467 (8)	C45—F46	1.332 (9)
C11—H11A	0.9900	C45—F48	1.334 (9)
C11—H11B	0.9900	C45—F47	1.340 (9)
C13—C14	1.418 (10)	Sb1—F13	1.868 (5)
C13—C18	1.418 (10)	Sb1—F16	1.870 (5)
C14—C15	1.394 (11)	Sb1—F14	1.873 (5)
C14—C19	1.523 (10)	Sb1—F12	1.876 (5)
C15—C16	1.374 (11)	Sb1—F11	1.879 (5)
C15—H15	0.9500	Sb1—F11	1.879 (5)
C16—C17	1.367 (11)	Sb1—F15	1.881 (5)
C16—C23	1.506 (11)	Cl1—C50	1.65 (2)
C17—C18	1.388 (11)	C50—H50A	0.9900
C17—H17	0.9500	C50—H50B	0.9900
C18—C27	1.510 (11)
C1—Pd1—N2	87.5 (3)	F25—C23—F24	107.8 (8)
C1—Pd1—N5	176.1 (3)	F26—C23—F24	105.3 (7)
N2—Pd1—N5	94.4 (2)	F25—C23—C16	112.5 (7)
C1—Pd1—P1	91.4 (2)	F26—C23—C16	111.1 (7)
N2—Pd1—P1	175.69 (19)	F24—C23—C16	112.6 (7)
N5—Pd1—P1	86.99 (17)	F30—C27—F28	106.8 (7)
O12—P1—C13	96.7 (3)	F30—C27—F29	107.1 (6)
O12—P1—C31	96.4 (3)	F28—C27—F29	106.2 (7)
C13—P1—C31	112.8 (3)	F30—C27—C18	112.7 (7)
O12—P1—Pd1	107.5 (2)	F28—C27—C18	111.7 (6)
C13—P1—Pd1	122.6 (2)	F29—C27—C18	112.0 (7)
C31—P1—Pd1	115.0 (2)	C36—C31—C32	115.5 (7)
Pd1—C1—H1A	109.5	C36—C31—P1	122.0 (6)
Pd1—C1—H1B	109.5	C32—C31—P1	119.5 (6)
H1A—C1—H1B	109.5	C33—C32—C31	121.6 (7)
Pd1—C1—H1C	109.5	C33—C32—C37	112.9 (7)
H1A—C1—H1C	109.5	C31—C32—C37	125.5 (7)
H1B—C1—H1C	109.5	C34—C33—C32	120.3 (8)
C3—N2—Pd1	175.1 (6)	C34—C33—H33	119.9
N2—C3—C4	179.5 (9)	C32—C33—H33	119.9
C3—C4—H4A	109.5	C35—C34—C33	120.0 (8)
C3—C4—H4B	109.5	C35—C34—C41	120.6 (8)
H4A—C4—H4B	109.5	C33—C34—C41	119.3 (8)
C3—C4—H4C	109.5	C34—C35—C36	120.5 (8)
H4A—C4—H4C	109.5	C34—C35—H35	119.8
H4B—C4—H4C	109.5	C36—C35—H35	119.8
C6—N5—C10	118.0 (7)	C35—C36—C31	121.4 (7)
C6—N5—Pd1	118.4 (5)	C35—C36—C45	110.3 (7)
C10—N5—Pd1	119.8 (5)	C31—C36—C45	128.2 (7)
N5—C6—C7	123.0 (7)	F40—C37—F38	108.0 (6)
N5—C6—H6	118.5	F40—C37—F39	106.2 (6)
C7—C6—H6	118.5	F38—C37—F39	105.4 (6)
C6—C7—C8	118.8 (7)	F40—C37—C32	114.0 (6)
C6—C7—H7	120.6	F38—C37—C32	113.5 (6)
C8—C7—H7	120.6	F39—C37—C32	109.1 (7)
C9—C8—C7	118.6 (8)	F42—C41—F44	111.0 (9)
C9—C8—H8	120.7	F42—C41—F43	103.6 (9)
C7—C8—H8	120.7	F44—C41—F43	105.5 (8)
C10—C9—C8	119.8 (7)	F42—C41—C34	112.8 (7)
C10—C9—H9	120.1	F44—C41—C34	112.9 (8)
C8—C9—H9	120.1	F43—C41—C34	110.3 (9)
N5—C10—C9	121.5 (7)	F46—C45—F48	106.3 (7)
N5—C10—C11	115.9 (7)	F46—C45—F47	107.4 (6)
C9—C10—C11	122.5 (7)	F48—C45—F47	106.3 (6)
O12—C11—C10	113.5 (6)	F46—C45—C36	109.5 (6)
O12—C11—H11A	108.9	F48—C45—C36	116.7 (6)
C10—C11—H11A	108.9	F47—C45—C36	110.2 (7)
O12—C11—H11B	108.9	F13—Sb1—F16	91.2 (3)
C10—C11—H11B	108.9	F13—Sb1—F14	90.0 (3)
H11A—C11—H11B	107.7	F16—Sb1—F14	89.7 (3)
C11—O12—P1	120.4 (4)	F13—Sb1—F12	90.2 (3)
C14—C13—C18	115.7 (6)	F16—Sb1—F12	91.8 (3)
C14—C13—P1	118.6 (5)	F14—Sb1—F12	178.5 (3)
C18—C13—P1	125.5 (5)	F13—Sb1—F11	179.2 (3)
C15—C14—C13	121.0 (7)	F16—Sb1—F11	89.6 (2)
C15—C14—C19	112.6 (6)	F14—Sb1—F11	89.8 (3)
C13—C14—C19	126.3 (7)	F12—Sb1—F11	90.0 (2)
C16—C15—C14	121.0 (7)	F13—Sb1—F11	179.2 (3)
C16—C15—H15	119.5	F16—Sb1—F11	89.6 (2)
C14—C15—H15	119.5	F14—Sb1—F11	89.8 (3)
C17—C16—C15	119.4 (7)	F12—Sb1—F11	90.0 (2)
C17—C16—C23	119.1 (7)	F11—Sb1—F11	0.0 (3)
C15—C16—C23	121.5 (7)	F13—Sb1—F15	90.1 (3)
C16—C17—C18	120.8 (7)	F16—Sb1—F15	178.4 (3)
C16—C17—H17	119.6	F14—Sb1—F15	89.3 (3)
C18—C17—H17	119.6	F12—Sb1—F15	89.2 (3)
C17—C18—C13	121.7 (7)	F11—Sb1—F15	89.1 (2)
C17—C18—C27	114.9 (7)	F11—Sb1—F15	89.1 (2)
C13—C18—C27	123.4 (7)	F11—F11—Sb1	0(10)
F21—C19—F20	107.6 (6)	C50—Cl1—C50i	74.4 (19)
F21—C19—F22	105.9 (6)	Cl1—C50—Cl1i	105.6 (19)
F20—C19—F22	106.3 (6)	Cl1—C50—H50A	110.6
F21—C19—C14	114.9 (6)	Cl1i—C50—H50A	110.6
F20—C19—C14	111.7 (6)	Cl1—C50—H50B	110.6
F22—C19—C14	109.8 (6)	Cl1i—C50—H50B	110.6
F25—C23—F26	107.0 (8)	H50A—C50—H50B	108.7
C1—Pd1—P1—O12	130.9 (3)	C15—C14—C19—F21	153.5 (6)
N2—Pd1—P1—O12	57 (3)	C13—C14—C19—F21	−26.5 (10)
N5—Pd1—P1—O12	−52.7 (3)	C15—C14—C19—F20	−83.6 (8)
C1—Pd1—P1—C13	20.6 (4)	C13—C14—C19—F20	96.5 (8)
N2—Pd1—P1—C13	−54 (3)	C15—C14—C19—F22	34.2 (9)
N5—Pd1—P1—C13	−163.0 (3)	C13—C14—C19—F22	−145.7 (7)
C1—Pd1—P1—C31	−123.1 (3)	C17—C16—C23—F25	60.7 (11)
N2—Pd1—P1—C31	163 (3)	C15—C16—C23—F25	−117.5 (9)
N5—Pd1—P1—C31	53.3 (3)	C17—C16—C23—F26	−59.3 (10)
C1—Pd1—N2—C3	15 (8)	C15—C16—C23—F26	122.5 (8)
N5—Pd1—N2—C3	−162 (8)	C17—C16—C23—F24	−177.2 (7)
P1—Pd1—N2—C3	89 (8)	C15—C16—C23—F24	4.6 (11)
Pd1—N2—C3—C4	132 (100)	C17—C18—C27—F30	−145.4 (7)
C1—Pd1—N5—C6	−62 (4)	C13—C18—C27—F30	35.2 (10)
N2—Pd1—N5—C6	56.6 (6)	C17—C18—C27—F28	−25.3 (10)
P1—Pd1—N5—C6	−127.5 (6)	C13—C18—C27—F28	155.4 (7)
C1—Pd1—N5—C10	96 (4)	C17—C18—C27—F29	93.7 (8)
N2—Pd1—N5—C10	−145.5 (6)	C13—C18—C27—F29	−85.6 (9)
P1—Pd1—N5—C10	30.4 (5)	O12—P1—C31—C36	134.8 (6)
C10—N5—C6—C7	−2.2 (11)	C13—P1—C31—C36	−125.2 (6)
Pd1—N5—C6—C7	156.1 (6)	Pd1—P1—C31—C36	22.1 (7)
N5—C6—C7—C8	−0.7 (12)	O12—P1—C31—C32	−25.0 (6)
C6—C7—C8—C9	2.9 (12)	C13—P1—C31—C32	75.1 (6)
C7—C8—C9—C10	−2.1 (12)	Pd1—P1—C31—C32	−137.7 (5)
C6—N5—C10—C9	3.0 (11)	C36—C31—C32—C33	−8.2 (11)
Pd1—N5—C10—C9	−155.0 (6)	P1—C31—C32—C33	152.8 (6)
C6—N5—C10—C11	−176.2 (6)	C36—C31—C32—C37	170.7 (7)
Pd1—N5—C10—C11	25.8 (8)	P1—C31—C32—C37	−28.2 (10)
C8—C9—C10—N5	−0.8 (12)	C31—C32—C33—C34	2.7 (12)
C8—C9—C10—C11	178.3 (7)	C37—C32—C33—C34	−176.4 (7)
N5—C10—C11—O12	−75.3 (8)	C32—C33—C34—C35	4.6 (13)
C9—C10—C11—O12	105.5 (8)	C32—C33—C34—C41	−175.9 (8)
C10—C11—O12—P1	40.9 (8)	C33—C34—C35—C36	−5.8 (13)
C13—P1—O12—C11	154.3 (5)	C41—C34—C35—C36	174.7 (8)
C31—P1—O12—C11	−91.7 (6)	C34—C35—C36—C31	−0.3 (12)
Pd1—P1—O12—C11	27.0 (6)	C34—C35—C36—C45	177.6 (7)
O12—P1—C13—C14	−45.0 (6)	C32—C31—C36—C35	7.0 (11)
C31—P1—C13—C14	−144.8 (5)	P1—C31—C36—C35	−153.5 (6)
Pd1—P1—C13—C14	70.7 (6)	C32—C31—C36—C45	−170.4 (7)
O12—P1—C13—C18	130.7 (6)	P1—C31—C36—C45	29.1 (11)
C31—P1—C13—C18	30.9 (7)	C33—C32—C37—F40	−79.3 (9)
Pd1—P1—C13—C18	−113.5 (6)	C31—C32—C37—F40	101.7 (9)
C18—C13—C14—C15	−4.7 (10)	C33—C32—C37—F38	156.4 (7)
P1—C13—C14—C15	171.4 (5)	C31—C32—C37—F38	−22.6 (11)
C18—C13—C14—C19	175.2 (7)	C33—C32—C37—F39	39.2 (9)
P1—C13—C14—C19	−8.6 (9)	C31—C32—C37—F39	−139.8 (7)
C13—C14—C15—C16	0.4 (11)	C35—C34—C41—F42	122.7 (11)
C19—C14—C15—C16	−179.5 (7)	C33—C34—C41—F42	−56.8 (14)
C14—C15—C16—C17	4.3 (11)	C35—C34—C41—F44	−4.1 (14)
C14—C15—C16—C23	−177.5 (7)	C33—C34—C41—F44	176.3 (9)
C15—C16—C17—C18	−4.5 (11)	C35—C34—C41—F43	−121.9 (10)
C23—C16—C17—C18	177.2 (7)	C33—C34—C41—F43	58.5 (11)
C16—C17—C18—C13	0.0 (11)	C35—C36—C45—F46	−61.1 (8)
C16—C17—C18—C27	−179.4 (7)	C31—C36—C45—F46	116.6 (8)
C14—C13—C18—C17	4.5 (10)	C35—C36—C45—F48	178.2 (7)
P1—C13—C18—C17	−171.3 (6)	C31—C36—C45—F48	−4.2 (12)
C14—C13—C18—C27	−176.1 (7)	C35—C36—C45—F47	56.8 (8)
P1—C13—C18—C27	8.0 (10)	C31—C36—C45—F47	−125.5 (8)

D—H···A	D—H	H···A	D···A	D—H···A
C4—H4C···F16ii	0.98	2.44	3.310 (10)	148
C11—H11B···F11	0.99	2.58	3.489 (9)	154
C9—H9···F11	0.95	2.47	3.345 (9)	152

Table 1

Hydrogen-bond geometry (Å, °)

D—H⋯A	D—H	H⋯A	D⋯A	D—H⋯A
C4—H4C⋯F16i	0.98	2.44	3.310 (10)	148
C11—H11B⋯F11	0.99	2.58	3.489 (9)	154
C9—H9⋯F11	0.95	2.47	3.345 (9)	152

Symmetry code: (i) .