Literature DB >> 21517056

Synthesis of the hydroxide cluster [Al13(μ3-OH)6(μ-OH)18(H2O)24]15+ from an aqueous solution.

Wei Wang1, Katherine M Wentz, Sophia E Hayes, Darren W Johnson, Douglas A Keszler.   

Abstract

A scalable synthesis of the "flat" tridecameric inorganic cluster [Al(13)(μ(3)-OH)(6)(μ-OH)(18)(H(2)O)(24)](15+) has been realized by treating an aqueous aluminum nitrate solution with a zinc-metal powder at room temperature. Single crystals and polycrystalline samples are readily obtained in yields exceeding 55% relative to the starting reagent Al(NO(3))(3). Products have been characterized by X-ray diffraction and solid-state (27)Al MAS and MQMAS NMR.
© 2011 American Chemical Society

Entities:  

Year:  2011        PMID： 21517056     DOI： 10.1021/ic200483q

Source DB:  PubMed          Journal:  Inorg Chem        ISSN： 0020-1669            Impact factor:   5.165


  3 in total

1.  Electrolytic synthesis of aqueous aluminum nanoclusters and in situ characterization by femtosecond Raman spectroscopy and computations.

Authors:  Wei Wang; Weimin Liu; I-Ya Chang; Lindsay A Wills; Lev N Zakharov; Shannon W Boettcher; Paul Ha-Yeon Cheong; Chong Fang; Douglas A Keszler
Journal:  Proc Natl Acad Sci U S A       Date:  2013-10-28       Impact factor: 11.205

2.  Group additivity-Pourbaix diagrams advocate thermodynamically stable nanoscale clusters in aqueous environments.

Authors:  Lindsay A Wills; Xiaohui Qu; I-Ya Chang; Thomas J L Mustard; Douglas A Keszler; Kristin A Persson; Paul Ha-Yeon Cheong
Journal:  Nat Commun       Date:  2017-06-15       Impact factor: 14.919

3.  Solution structural characterization of an array of nanoscale aqueous inorganic Ga13-x In x (0 ≤ x ≤ 6) clusters by 1H-NMR and QM computations.

Authors:  Anna F Oliveri; Lindsay A Wills; Caitlyn R Hazlett; Matthew E Carnes; I-Ya Chang; Paul Ha-Yeon Cheong; Darren W Johnson
Journal:  Chem Sci       Date:  2015-04-28       Impact factor: 9.825
  3 in total

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