Literature DB >> 21517023

Hydroalkoxylation catalyzed by a gold(I) complex encapsulated in a supramolecular host.

Z Jane Wang1, Casey J Brown, Robert G Bergman, Kenneth N Raymond, F Dean Toste.   

Abstract

Gold(I)-phosphine complexes are readily encapsulated by a tetrahedral supramolecular host (Ga(4)L(6)). We have investigated the catalytic activity of the resulting complexes for the intramolecular hydroalkoxylation of allenes. The catalytic activity of Me(3)PAuBr was increased 8-fold by encapsulation, as determined by initial rate kinetics, and we observed up to 67 catalytic turnovers by Me(3)PAu(+) encapsulated in Ga(4)L(6).
© 2011 American Chemical Society

Entities:  

Year:  2011        PMID： 21517023     DOI： 10.1021/ja202055v

Source DB:  PubMed          Journal:  J Am Chem Soc        ISSN： 0002-7863            Impact factor:   15.419


  20 in total

Review 1.  Supramolecular coordination: self-assembly of finite two- and three-dimensional ensembles.

Authors:  Rajesh Chakrabarty; Partha Sarathi Mukherjee; Peter J Stang
Journal:  Chem Rev       Date:  2011-08-24       Impact factor: 60.622

2.  A supramolecular approach to combining enzymatic and transition metal catalysis.

Authors:  Z Jane Wang; Kristen N Clary; Robert G Bergman; Kenneth N Raymond; F Dean Toste
Journal:  Nat Chem       Date:  2013-01-06       Impact factor: 24.427

Review 3.  The Cation-π Interaction in Small-Molecule Catalysis.

Authors:  C Rose Kennedy; Song Lin; Eric N Jacobsen
Journal:  Angew Chem Int Ed Engl       Date:  2016-06-22       Impact factor: 15.336

4.  Design and Applications of Water-Soluble Coordination Cages.

Authors:  Edmundo G Percástegui; Tanya K Ronson; Jonathan R Nitschke
Journal:  Chem Rev       Date:  2020-11-25       Impact factor: 60.622

5.  Self-assembled nanospheres with multiple endohedral binding sites pre-organize catalysts and substrates for highly efficient reactions.

Authors:  Qi-Qiang Wang; Sergio Gonell; Stefan H A M Leenders; Maximilian Dürr; Ivana Ivanović-Burmazović; Joost N H Reek
Journal:  Nat Chem       Date:  2016-01-11       Impact factor: 24.427

6.  Switchable catalysis with a light-responsive cavitand.

Authors:  Orion B Berryman; Aaron C Sather; Agustí Lledó; Julius Rebek
Journal:  Angew Chem Int Ed Engl       Date:  2011-09-08       Impact factor: 15.336

7.  Dynamics of a supramolecular capsule assembly with pyrene.

Authors:  Hao Tang; Carla Santos de Oliveira; Gage Sonntag; Corinne L D Gibb; Bruce C Gibb; Cornelia Bohne
Journal:  J Am Chem Soc       Date:  2012-03-19       Impact factor: 15.419

8.  Origin of the Rate Acceleration in the C-C Reductive Elimination from Pt(IV)-complex in a [Ga4 L6 ]12- Supramolecular Metallocage.

Authors:  Gantulga Norjmaa; Jean-Didier Maréchal; Gregori Ujaque
Journal:  Chemistry       Date:  2021-10-13       Impact factor: 5.020

9.  Supramolecular Host-Selective Activation of Iodoarenes by Encapsulated Organometallics.

Authors:  Trandon A Bender; Mariko Morimoto; Robert G Bergman; Kenneth N Raymond; F Dean Toste
Journal:  J Am Chem Soc       Date:  2019-01-22       Impact factor: 15.419

10.  Electrostatic control of peptide side-chain reactivity using amphiphilic homopolymer-based supramolecular assemblies.

Authors:  Feng Wang; Andrea Gomez-Escudero; Rajasekhar R Ramireddy; Gladys Murage; S Thayumanavan; Richard W Vachet
Journal:  J Am Chem Soc       Date:  2013-09-11       Impact factor: 15.419
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