| Literature DB >> 21510616 |
Noriaki Shohji1, Tsuyoshi Kawaji, Sentaro Okamoto.
Abstract
A low-valent titanium generated in situ from Ti(O-i-Pr)(4), Me(3)SiCl, and Mg powder in THF reacted with aryl- and alkyl-sulfonamides of aryl and alkyl amines in a reductive N-S/S-O/S-C bond cleaving pathway to provide the corresponding amines and hydrocarbons (and thiols) derived from the sulfonyl moiety. The reagent could also cleave sulfonates to the corresponding alcohols.Entities:
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Year: 2011 PMID： 21510616 DOI： 10.1021/ol200740r
Source DB: PubMed Journal: Org Lett ISSN： 1523-7052 Impact factor: 6.005