| Literature DB >> 21507418 |
Rongzhi Chen1, Chunyi Zhi, Huang Yang, Yoshio Bando, Zhenya Zhang, Norio Sugiur, Dmitri Golberg.
Abstract
Multiwalled boron nitride nanotubes (BNNTs) functionalized with Fe(3)O(4) nanoparticles (NPs) were used for arsenic removal from water solutions. Sonication followed by a heating process was developed to in situ functionalize Fe(3)O(4) NPs onto a tube surface. A batch of adsorption experiments conducted at neutral pH (6.9) and room temperature (25 °C) and using the developed nanocomposites revealed effective arsenic (V) removal. The Langmuir, Freundlich, and Dubinin-Radushkevich adsorption isotherms were measured for a range of As(V) initial concentrations from 1 to 40 mg/L under the same conditions. The equilibrium data well fitted all isotherms, indicating that the mechanism for As(V) adsorption was a combination of chemical complexation and physical electrostatic attraction with a slight preference for chemisorption. The magnetite NPs functionalized on BNNTs led to a simple and rapid separation of magnetic metal-loaded adsorbents from the treated water under an external magnetic field.Entities:
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Year: 2011 PMID: 21507418 DOI: 10.1016/j.jcis.2011.02.071
Source DB: PubMed Journal: J Colloid Interface Sci ISSN: 0021-9797 Impact factor: 8.128