Literature DB >> 21506005

Modern developments in aryl radical chemistry.

Gerald Pratsch1, Markus R Heinrich.   

Abstract

This review summarizes recent advances in the field of aryl radical chemistry. In particular, modern developments of the well-known Meerwein, Pschorr, and Gomberg-Bachmann reactions are presented along with new applications in natural product syntheses. Among the methods for the generation of aryl radicals, tin hydrides play a predominant role, but more and more attractive and promising alternatives are beginning to emerge.

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Year:  2012        PMID： 21506005     DOI： 10.1007/128_2011_127

Source DB:  PubMed          Journal:  Top Curr Chem        ISSN： 0340-1022


  5 in total

1.  Phenyl hydrazine as initiator for direct arene C-H arylation via base promoted homolytic aromatic substitution.

Authors:  Abhishek Dewanji; Sandip Murarka; Dennis P Curran; Armido Studer
Journal:  Org Lett       Date:  2013-11-19       Impact factor: 6.005

2.  K2S2O8 mediated C-3 arylation of quinoxalin-2(1H)-ones under metal-, photocatalyst- and light-free conditions.

Authors:  Nibedita Baruah Dutta; Mayurakhi Bhuyan; Gakul Baishya
Journal:  RSC Adv       Date:  2020-01-22       Impact factor: 4.036

3.  Cathodic Radical Cyclisation of Aryl Halides Using a Strongly-Reducing Catalytic Mediator in Flow.

Authors:  Ana A Folgueiras-Amador; Alexander E Teuten; Mateo Salam-Perez; James E Pearce; Guy Denuault; Derek Pletcher; Philip J Parsons; David C Harrowven; Richard C D Brown
Journal:  Angew Chem Int Ed Engl       Date:  2022-07-18       Impact factor: 16.823

4.  Interplay of ortho- with spiro-cyclisation during iminyl radical closures onto arenes and heteroarenes.

Authors:  Roy T McBurney; John C Walton
Journal:  Beilstein J Org Chem       Date:  2013-06-04       Impact factor: 2.883

5.  A case of chain propagation: α-aminoalkyl radicals as initiators for aryl radical chemistry.

Authors:  Timothée Constantin; Fabio Juliá; Nadeem S Sheikh; Daniele Leonori
Journal:  Chem Sci       Date:  2020-10-20       Impact factor: 9.825
  5 in total

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