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Literature DB >> 21500412

Metal-catalyzed oxidations of C-H to C-N bonds.

Abstract

This chapter offers a general review of selective methods for the oxidative conversion of C-H to C-N bonds. Special focus has been given to the many disparate catalyst types that are capable of promoting this unique transformation.

Entities: Chemical

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Year: 2010 PMID： 21500412 DOI： 10.1007/128_2009_19

Source DB: PubMed Journal: Top Curr Chem ISSN： 0340-1022

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Cited

41 in total

1. Intermolecular Ritter-type C-H amination of unactivated sp3 carbons.

Authors: Quentin Michaudel; Damien Thevenet; Phil S Baran
Journal: J Am Chem Soc Date: 2012-01-27 Impact factor: 15.419

2. Chemo- and Enantioselective Intramolecular Silver-Catalyzed Aziridinations.

Authors: Minsoo Ju; Cale D Weatherly; Ilia A Guzei; Jennifer M Schomaker
Journal: Angew Chem Int Ed Engl Date: 2017-07-12 Impact factor: 15.336

3. Palladium(0)-catalyzed intermolecular amination of unactivated C(sp³)-H bonds.

Authors: Jun Pan; Mingjuan Su; Stephen L Buchwald
Journal: Angew Chem Int Ed Engl Date: 2011-08-02 Impact factor: 15.336

4. Application of diazene-directed fragment assembly to the total synthesis and stereochemical assignment of (+)-desmethyl-meso-chimonanthine and related heterodimeric alkaloids.

Authors: Stephen P Lathrop; Mohammad Movassaghi
Journal: Chem Sci Date: 2014-01-01 Impact factor: 9.825

Metal-catalyzed oxidations of C-H to C-N bonds.

1. Intermolecular Ritter-type C-H amination of unactivated sp3 carbons.

2. Chemo- and Enantioselective Intramolecular Silver-Catalyzed Aziridinations.

3. Palladium(0)-catalyzed intermolecular amination of unactivated C(sp³)-H bonds.

4. Application of diazene-directed fragment assembly to the total synthesis and stereochemical assignment of (+)-desmethyl-meso-chimonanthine and related heterodimeric alkaloids.

5. Capturing fleeting intermediates in a catalytic C-H amination reaction cycle.

6. Chemoselective amination of propargylic C(sp³)-H bonds by cobalt(II)-based metalloradical catalysis.

7. Synthesis and reactivity of unique heterocyclic structures en route to substituted diamines.

8. Syntheses of Cyclic Guanidine-Containing Natural Products.

9. Directed amination of non-acidic arene C-H bonds by a copper-silver catalytic system.

10. Metal-Catalyzed and Metal-Free Intermolecular Amination of Light Alkanes and Benzenes.