Literature DB >> 21495619

General route to symmetric and asymmetric meso-CF3-3(5)-aryl(hetaryl)- and 3,5-diaryl(dihetaryl)-BODIPY dyes.

Lubov N Sobenina1, Alexander M Vasil'tsov, Olga V Petrova, Konstantin B Petrushenko, Igor A Ushakov, Gilles Clavier, Rachel Meallet-Renault, Albina I Mikhaleva, Boris A Trofimov.   

Abstract

A general efficient route to hitherto inaccessible symmetric and asymmetric meso-CF(3)-BODIPY dyes has been developed. The key stages include the reduction of available 2-trifluoroacetylpyrroles to the corresponding alcohols which are further condensed with pyrroles. The method allows the BODIPY with 3(5)aryl(hetaryl) and 3,5-diaryl(hetaryl) substituents to be readily assembled. The BODIPY dyes synthesized fluoresce (Φ(f) = 0.56-1.00) in the 560-680 nm region.

Entities:  

Year:  2011        PMID: 21495619     DOI: 10.1021/ol200360f

Source DB:  PubMed          Journal:  Org Lett        ISSN: 1523-7052            Impact factor:   6.005


  2 in total

Review 1.  Recent Strides in the Transition Metal-Free Cross-Coupling of Haloacetylenes with Electron-Rich Heterocycles in Solid Media.

Authors:  Lyubov' N Sobenina; Boris A Trofimov
Journal:  Molecules       Date:  2020-05-27       Impact factor: 4.411

2.  Application of meso-CF3-Fluorophore BODIPY with Phenyl and Pyrazolyl Substituents for Lifetime Visualization of Lysosomes.

Authors:  Irina S Trukhan; Denis N Tomilin; Nataliya N Dremina; Lyubov N Sobenina; Michael G Shurygin; Konstantin B Petrushenko; Igor K Petrushenko; Boris A Trofimov; Irina A Shurygina
Journal:  Molecules       Date:  2022-08-07       Impact factor: 4.927

  2 in total

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