Literature DB >> 21455512

Emerging supramolecular synthons: C-H···π(chelate) interactions in metal bis(1,1-dithiolates).

Edward R T Tiekink1, Julio Zukerman-Schpector.   

Abstract

Crystal structures of transition and main group element 1,1-dithiolates are shown to be partially sustained by C-H···π(chelate) interactions. For the planar binary bisdithiocarbamates, C-H···π(MS(2)C) interactions lead to aggregation patterns ranging from a 0-D four molecule aggregate to a 3-D architecture but with the majority of structures featuring 1-D or 2-D supramolecular assemblies. This journal is © The Royal Society of Chemistry 2011

Entities:  

Year:  2011        PMID： 21455512     DOI： 10.1039/c1cc11173f

Source DB:  PubMed          Journal:  Chem Commun (Camb)        ISSN： 1359-7345            Impact factor:   6.222


  11 in total

1.  Bis(N-isopropyl-N-methyl-dithio-carbamato-κS,S')(1,10-phenanthroline-κN,N')zinc.

Authors:  Nor Asiken Abdul Wahab; Ibrahim Baba; Mohamed Ibrahim Mohamed Tahir; Edward R T Tiekink
Journal:  Acta Crystallogr Sect E Struct Rep Online       Date:  2011-04-07

2.  [μ2-trans-1,2-Bis-(pyridin-4-yl)ethene-κ(2) N:N']bis-{[1,2-bis-(pyridin-4-yl)ethene-κN]bis-[N-(2-hydroxy-eth-yl)-N-iso-propyl-dithio-carbamato-κ(2) S,S']cadmium} aceto-nitrile tetra-solvate: crystal structure and Hirshfeld surface analysis.

Authors:  Mukesh M Jotani; Pavel Poplaukhin; Hadi D Arman; Edward R T Tiekink
Journal:  Acta Crystallogr E Crystallogr Commun       Date:  2016-07-12

3.  An unprecedented binuclear cadmium di-thio-carbamate adduct: bis-[μ2-N-(2-hydroxy-eth-yl)-N-iso-propyl-carbamodi-thio-ato-κ3S:S,S']bis-{[N-(2-hydroxy-eth-yl)-N-iso-propyl-carbamodi-thio-ato-κ2S,S'](3-{(1E)-[(E)-2-(pyridin-3-yl-methyl-idene)hydrazin-1-yl-idene]meth-yl}pyridine-κN)cadmium]} dihydrate.

Authors:  Hadi D Arman; Pavel Poplaukhin; Edward R T Tiekink
Journal:  Acta Crystallogr E Crystallogr Commun       Date:  2016-08-02

4.  Bis(N,N-di-ethyl-dithio-carbamato-κ2S,S')(3-hy-droxy-pyridine-κN)zinc and bis-[N-(2-hy-droxy-eth-yl)-N-methyldithio-carbamato-κ2S,S'](3-hy-droxy-pyridine-κN)zinc: crystal structures and Hirshfeld surface analysis.

Authors:  Mukesh M Jotani; Hadi D Arman; Pavel Poplaukhin; Edward R T Tiekink
Journal:  Acta Crystallogr E Crystallogr Commun       Date:  2016-11-01

5.  Crystal structures of {μ2-N,N'-bis-[(pyridin-3-yl)meth-yl]ethanedi-amide}tetra-kis-(di-methyl-carbamodi-thio-ato)dizinc(II) di-methyl-formamide disolvate and {μ2-N,N'-bis-[(pyridin-3-yl)meth-yl]ethanedi-amide}tetra-kis-(di-n-propyl-carbamodi-thio-ato)dizinc(II).

Authors:  Hadi D Arman; Pavel Poplaukhin; Edward R T Tiekink
Journal:  Acta Crystallogr E Crystallogr Commun       Date:  2017-09-19

6.  Crystal structure of bis-[N-(2-hy-droxy-eth-yl)-N-methyl-dithio-carbamato-κ2S,S'](pyridine)-zinc(II) pyridine monosolvate and its N-ethyl analogue.

Authors:  Pavel Poplaukhin; Edward R T Tiekink
Journal:  Acta Crystallogr E Crystallogr Commun       Date:  2017-07-21

7.  A one-dimensional coordination polymer, catena-poly[[[[N-ethyl-N-(pyridin-4-ylmeth-yl)di-thio-carbamato-κ2S,S']zinc(II)]-μ2-N-ethyl-N-(pyridin-4-ylmeth-yl)di-thio-carbamato-κ3S,S':N] 4-methyl-pyridine hemisolvate].

Authors:  Pavel Poplaukhin; Hadi D Arman; Edward R T Tiekink
Journal:  Acta Crystallogr E Crystallogr Commun       Date:  2017-07-13

8.  μ3-Chlorido-μ2-chlorido-(μ3-pyrrolidine-1-carbo-dithio-ato-κ4S:S,S':S')tris-[(tri-ethyl-phosphane-κP)copper(I)]: crystal structure and Hirshfeld surface analysis.

Authors:  Yi Jiun Tan; Chien Ing Yeo; Nathan R Halcovitch; Mukesh M Jotani; Edward R T Tiekink
Journal:  Acta Crystallogr E Crystallogr Commun       Date:  2017-04-18

9.  Crystal structures of (2,2'-bipyridyl-κ(2) N,N')bis-[N,N-bis-(2-hydroxy-eth-yl)di-thio-carbamato-κ(2) S,S']zinc dihydrate and (2,2'-bipyridyl-κ(2) N,N')bis-[N-(2-hydroxy-eth-yl)-N-iso-propyl-dithio-carbamato-κ(2) S,S']zinc.

Authors:  Siti Artikah M Safbri; Siti Nadiah Abdul Halim; Edward R T Tiekink
Journal:  Acta Crystallogr E Crystallogr Commun       Date:  2016-01-20

10.  Crystal structure of (4,4'-bipyridyl-κN)bis-[N-(2-hydroxy-ethyl)-N-iso-propyl-dithio-carbamato-κ2S,S']zinc(II)-4,4'-bipyridyl (2/1) and its isostructural cadmium(II) analogue.

Authors:  Yee Seng Tan; Edward R T Tiekink
Journal:  Acta Crystallogr E Crystallogr Commun       Date:  2017-10-13
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