Literature DB >> 21452878

Exploring the uranyl organometallic chemistry: from single to double uranium-carbon bonds.

Jean-Christophe Tourneux1, Jean-Claude Berthet, Thibault Cantat, Pierre Thuéry, Nicolas Mézailles, Michel Ephritikhine.   

Abstract

Uranyl organometallic complexes featuring uranium(VI)-carbon single and double bonds have been obtained from uranyl UO(2)X(2) precursors by avoiding reduction of the metal center. X-ray diffraction and density functional theory analyses of these complexes showed that the U-C and U=C bonds are polarized toward the nucleophilic carbon.

Entities:  

Year:  2011        PMID： 21452878     DOI： 10.1021/ja201276h

Source DB:  PubMed          Journal:  J Am Chem Soc        ISSN： 0002-7863            Impact factor:   15.419


  11 in total

1.  Triamidoamine uranium(IV)-arsenic complexes containing one-, two- and threefold U-As bonding interactions.

Authors:  Benedict M Gardner; Gábor Balázs; Manfred Scheer; Floriana Tuna; Eric J L McInnes; Jonathan McMaster; William Lewis; Alexander J Blake; Stephen T Liddle
Journal:  Nat Chem       Date:  2015-06-15       Impact factor: 24.427

2.  Isolation and characterization of a uranium(VI)-nitride triple bond.

Authors:  David M King; Floriana Tuna; Eric J L McInnes; Jonathan McMaster; William Lewis; Alexander J Blake; Stephen T Liddle
Journal:  Nat Chem       Date:  2013-05-05       Impact factor: 24.427

3.  The ketimide ligand is not just an inert spectator: heteroallene insertion reactivity of an actinide-ketimide linkage in a thorium carbene amide ketimide complex.

Authors:  Erli Lu; William Lewis; Alexander J Blake; Stephen T Liddle
Journal:  Angew Chem Int Ed Engl       Date:  2014-07-07       Impact factor: 15.336

4.  Uranium(III)-carbon multiple bonding supported by arene δ-bonding in mixed-valence hexauranium nanometre-scale rings.

Authors:  Ashley J Wooles; David P Mills; Floriana Tuna; Eric J L McInnes; Gareth T W Law; Adam J Fuller; Felipe Kremer; Mark Ridgway; William Lewis; Laura Gagliardi; Bess Vlaisavljevich; Stephen T Liddle
Journal:  Nat Commun       Date:  2018-05-29       Impact factor: 14.919

5.  Double dative bond between divalent carbon(0) and uranium.

Authors:  Wei Su; Sudip Pan; Xiong Sun; Shuao Wang; Lili Zhao; Gernot Frenking; Congqing Zhu
Journal:  Nat Commun       Date:  2018-11-27       Impact factor: 14.919

6.  Silyl-Phosphino-Carbene Complexes of Uranium(IV).

Authors:  Erli Lu; Josef T Boronski; Matthew Gregson; Ashley J Wooles; Stephen T Liddle
Journal:  Angew Chem Int Ed Engl       Date:  2018-03-26       Impact factor: 15.336

7.  Thorium-phosphorus triamidoamine complexes containing Th-P single- and multiple-bond interactions.

Authors:  Elizabeth P Wildman; Gábor Balázs; Ashley J Wooles; Manfred Scheer; Stephen T Liddle
Journal:  Nat Commun       Date:  2016-09-29       Impact factor: 14.919

8.  Thorium-ligand multiple bonds via reductive deprotection of a trityl group.

Authors:  Danil E Smiles; Guang Wu; Nikolas Kaltsoyannis; Trevor W Hayton
Journal:  Chem Sci       Date:  2015-04-30       Impact factor: 9.825

9.  A diuranium carbide cluster stabilized inside a C80 fullerene cage.

Authors:  Xingxing Zhang; Wanlu Li; Lai Feng; Xin Chen; Andreas Hansen; Stefan Grimme; Skye Fortier; Dumitru-Claudiu Sergentu; Thomas J Duignan; Jochen Autschbach; Shuao Wang; Yaofeng Wang; Giorgios Velkos; Alexey A Popov; Nabi Aghdassi; Steffen Duhm; Xiaohong Li; Jun Li; Luis Echegoyen; W H Eugen Schwarz; Ning Chen
Journal:  Nat Commun       Date:  2018-07-16       Impact factor: 14.919

10.  Reappraising Schmidpeter's bis(iminophosphoranyl)phosphides: coordination to transition metals and bonding analysis.

Authors:  Adrien T Normand; E Daiann Sosa Carrizo; Corentin Magnoux; Esteban Lobato; Hélène Cattey; Philippe Richard; Stéphane Brandès; Charles H Devillers; Anthony Romieu; Pierre Le Gendre; Paul Fleurat-Lessard
Journal:  Chem Sci       Date:  2020-10-26       Impact factor: 9.825
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