Literature DB >> 21449555

Stereoselective coupling reaction of dimethylzinc and alkyne toward nickelacycles.

Takamichi Mori1, Toshiyuki Nakamura, Masanari Kimura.   

Abstract

Ni catalyst promotes the three-component coupling reaction of vinyloxacyclopropane, alkyne, and dimethylzinc to provide 2,5-heptadienyl alcohol in high yields. Vinylcyclopropane also participates in a similar three-component coupling reaction to afford dimethyl (α-heptadienyl)malonate with excellent E-stereoselectivity.

Entities:  

Year:  2011        PMID: 21449555     DOI: 10.1021/ol2005352

Source DB:  PubMed          Journal:  Org Lett        ISSN: 1523-7052            Impact factor:   6.005


  2 in total

1.  An approach to mimicking the sesquiterpene cyclase phase by nickel-promoted diene/alkyne cooligomerization.

Authors:  Dane Holte; Daniel C G Götz; Phil S Baran
Journal:  J Org Chem       Date:  2012-01-03       Impact factor: 4.354

2.  Transition Metal-Catalyzed Selective Carbon-Carbon Bond Cleavage of Vinylcyclopropanes in Cycloaddition Reactions.

Authors:  Jianhua Wang; Stephanie A Blaszczyk; Xiaoxun Li; Weiping Tang
Journal:  Chem Rev       Date:  2020-08-05       Impact factor: 72.087

  2 in total

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