| Literature DB >> 21446662 |
Haibo Tan1, Chao Zheng, Zheng Liu, David Zhigang Wang.
Abstract
Simple exposure to sunlight is sufficient for triggering photochemical [2 + 2] cycloaddition-Cope or radical rearrangement cascades in the naturally occurring methyl linderone, leading to efficient biomimetic total syntheses of linderaspirone A and bi-linderone, two recently discovered bioactive spirocyclopentenedione natural products.Entities:
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Year: 2011 PMID: 21446662 DOI: 10.1021/ol200418e
Source DB: PubMed Journal: Org Lett ISSN: 1523-7052 Impact factor: 6.005