Literature DB >> 21438514

Reducing the cost, smell, and toxicity of the Barton reductive decarboxylation: chloroform as the hydrogen atom source.

Eun Jung Ko1, G Paul Savage, Craig M Williams, John Tsanaktsidis.   

Abstract

When used as solvent, chloroform was found to act as a hydrogen atom donor in Barton reductive decarboxylation reactions. Chloroform offers a substantial practical advantage over pre-existing hydrogen atom donors.
© 2011 American Chemical Society

Entities:  

Year:  2011        PMID： 21438514     DOI： 10.1021/ol200290m

Source DB:  PubMed          Journal:  Org Lett        ISSN： 1523-7052            Impact factor:   6.005


  5 in total

1.  Nickel-Catalyzed Barton Decarboxylation and Giese Reactions: A Practical Take on Classic Transforms.

Authors:  Tian Qin; Lara R Malins; Jacob T Edwards; Rohan R Merchant; Alexander J E Novak; Jacob Z Zhong; Riley B Mills; Ming Yan; Changxia Yuan; Martin D Eastgate; Phil S Baran
Journal:  Angew Chem Int Ed Engl       Date:  2016-12-16       Impact factor: 15.336

2.  Asymmetric Formal Total Synthesis of the Stemofoline Alkaloids: The Evolution, Development and Application of a Catalytic Dipolar Cycloaddition Cascade.

Authors:  Charles S Shanahan; Chao Fang; Daniel H Paull; Stephen F Martin
Journal:  Tetrahedron       Date:  2013-09-09       Impact factor: 2.457

3.  Enantioselective formal total syntheses of didehydrostemofoline and isodidehydrostemofoline through a catalytic dipolar cycloaddition cascade.

Authors:  Chao Fang; Charles S Shanahan; Daniel H Paull; Stephen F Martin
Journal:  Angew Chem Int Ed Engl       Date:  2012-09-17       Impact factor: 15.336

4.  Direct Hydrodecarboxylation of Aliphatic Carboxylic Acids: Metal- and Light-Free.

Authors:  Euan B McLean; David T Mooney; David J Burns; Ai-Lan Lee
Journal:  Org Lett       Date:  2022-01-07       Impact factor: 6.005

5.  Identification of (Z)-8-Heptadecene and n-Pentadecane as Electrophysiologically Active Compounds in Ophrys insectifera and Its Argogorytes Pollinator.

Authors:  Björn Bohman; Alyssa M Weinstein; Raimondas Mozuraitis; Gavin R Flematti; Anna-Karin Borg-Karlson
Journal:  Int J Mol Sci       Date:  2020-01-17       Impact factor: 5.923
  5 in total

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