Recent advances in hydrogen-bonded hexameric encapsulation complexes.

Basic research in the chemistry of hexameric resorcin[4]arenes and pyrogallol[4]arenes during the last decade is reviewed. Applications of NMR methods to determine solution structures, host guest properties and exchange dynamics are discussed. The scientific issue is the behavior of molecules in small spaces; the challenge is to translate this information to practical applications in, say, catalysis or transport. © The Royal Society of Chemistry 2011