Literature DB >> 21431158

Effect of NH2 and CF3 functionalization on the hydrogen sorption properties of MOFs.

Claudia Zlotea1, Delphine Phanon, Matjaz Mazaj, Daniela Heurtaux, Vincent Guillerm, Christian Serre, Patricia Horcajada, Thomas Devic, Emmanuel Magnier, Fermin Cuevas, Gérard Férey, Philip L Llewellyn, Michel Latroche.   

Abstract

The hydrogen adsorption capacity and heat of adsorption at 77 K have been evaluated for several porous metal terephthalate MOFs (MIL-53(Fe), MIL-125(Ti) and UiO-66(Zr)), as well as in their -NH(2) and -(CF(3))(2) functionalized isoreticular structures. The capacity of hydrogen is basically related to the textural properties of the solids and not to their composition. The heats of adsorption at low coverage are on the whole close to those usually reported for MOFs (6-7 kJ mol(-1)), except for the UiO-66(Zr) and MIL-53(Fe)-(CF(3))(2) analogues, whereas the presence of Lewis acid sites and/or a confinement effect enhances significantly the strength of interaction with hydrogen.

Entities:  

Year:  2011        PMID： 21431158     DOI： 10.1039/c1dt10115c

Source DB:  PubMed          Journal:  Dalton Trans        ISSN： 1477-9226            Impact factor:   4.390


  10 in total

1.  Process Optimization for Catalytic Oxidation of Dibenzothiophene over UiO-66-NH2 by Using a Response Surface Methodology.

Authors:  Bijan Barghi; Martin Jürisoo; Maria Volokhova; Liis Seinberg; Indrek Reile; Valdek Mikli; Allan Niidu
Journal:  ACS Omega       Date:  2022-05-02

Review 2.  Hydrophobic Metal-Organic Frameworks: Assessment, Construction, and Diverse Applications.

Authors:  Lin-Hua Xie; Ming-Ming Xu; Xiao-Min Liu; Min-Jian Zhao; Jian-Rong Li
Journal:  Adv Sci (Weinh)       Date:  2020-01-19       Impact factor: 16.806

3.  Mechanochemical and solvent-free assembly of zirconium-based metal-organic frameworks.

Authors:  Krunoslav Užarević; Timothy C Wang; Su-Young Moon; Athena M Fidelli; Joseph T Hupp; Omar K Farha; Tomislav Friščić
Journal:  Chem Commun (Camb)       Date:  2016-02-04       Impact factor: 6.222

4.  Functional metal-organic framework boosting lithium metal anode performance via chemical interactions.

Authors:  Wen Liu; Yingying Mi; Zhe Weng; Yiren Zhong; Zishan Wu; Hailiang Wang
Journal:  Chem Sci       Date:  2017-04-18       Impact factor: 9.825

5.  NH2-MIL-125(Ti)-derived porous cages of titanium oxides to support Pt-Co alloys for chemoselective hydrogenation reactions.

Authors:  Zhizhi Gu; Liyong Chen; Xuezhao Li; Lin Chen; Yingyue Zhang; Chunying Duan
Journal:  Chem Sci       Date:  2018-12-12       Impact factor: 9.825

6.  Ab Initio Study of Hydrostable Metal-Organic Frameworks for Postsynthetic Modification and Tuning toward Practical Applications.

Authors:  Uchenna A Anene; S Pamir Alpay
Journal:  ACS Omega       Date:  2022-02-16

7.  New functionalized MIL-53(In) solids: syntheses, characterization, sorption, and structural flexibility.

Authors:  Lei Wu; Gérald Chaplais; Ming Xue; Shilun Qiu; Joël Patarin; Angélique Simon-Masseron; Huaxin Chen
Journal:  RSC Adv       Date:  2019-01-15       Impact factor: 4.036

Review 8.  Stable Metal-Organic Frameworks with Group 4 Metals: Current Status and Trends.

Authors:  Shuai Yuan; Jun-Sheng Qin; Christina T Lollar; Hong-Cai Zhou
Journal:  ACS Cent Sci       Date:  2018-03-26       Impact factor: 14.553

9.  Nanometric MIL-125-NH₂ Metal-Organic Framework as a Potential Nerve Agent Antidote Carrier.

Authors:  Sérgio M F Vilela; Pablo Salcedo-Abraira; Isabelle Colinet; Fabrice Salles; Martijn C de Koning; Marloes J A Joosen; Christian Serre; Patricia Horcajada
Journal:  Nanomaterials (Basel)       Date:  2017-10-12       Impact factor: 5.076

10.  Phase-Selective Microwave Assisted Synthesis of Iron(III) Aminoterephthalate MOFs.

Authors:  Ana Arenas-Vivo; David Avila; Patricia Horcajada
Journal:  Materials (Basel)       Date:  2020-03-23       Impact factor: 3.623
  10 in total

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