Warning: Undefined array key "mm" in /www/wwwroot/www.ai-bt.com/si.php on line 10 Deprecated: trim(): Passing null to parameter #1 ($string) of type string is deprecated in /www/wwwroot/www.ai-bt.com/si.php on line 10 Synthesis of Oxazolidinone and Tosyl Enamines by Tertiary Amine Catalysis.

Literature DB >> 21423880

Synthesis of Oxazolidinone and Tosyl Enamines by Tertiary Amine Catalysis.

Nicholas A Eddy¹, Peter D Morse, Martha D Morton, Gabriel Fenteany.

Abstract

A procedure for the synthesis of oxazolidinone and tosyl enamines is reported. Alkynoyl oxazolidinones and tosyl imides undergo reaction to form enamines in the presence of catalytic amounts of tertiary amines. The data suggest that an amide anion is formed during the reaction, which undergoes conjugate addition to form the final product.

Entities: Chemical Disease Gene

Year: 2011 PMID： 21423880 PMCID： PMC3059314 DOI： 10.1055/s-0030-1259561

Source DB: PubMed Journal: Synlett ISSN： 0936-5214 Impact factor: 2.454

Keyword Cloud
References

21 in total

1. Direct catalytic asymmetric enolexo aldolizations.

Authors: Chandrakala Pidathala; Linh Hoang; Nicola Vignola; Benjamin List
Journal: Angew Chem Int Ed Engl Date: 2003-06-23 Impact factor: 15.336

2. A metal-free transfer hydrogenation: organocatalytic conjugate reduction of alpha,beta-unsaturated aldehydes.

Authors: Jung Woon Yang; Maria T Hechavarria Fonseca; Benjamin List
Journal: Angew Chem Int Ed Engl Date: 2004-12-10 Impact factor: 15.336

Review 3. Asymmetric enamine catalysis.

Authors: Santanu Mukherjee; Jung Woon Yang; Sebastian Hoffmann; Benjamin List
Journal: Chem Rev Date: 2007-12 Impact factor: 60.622

4. A chemical inhibitor reveals the role of Raf kinase inhibitor protein in cell migration.

Authors: Shoutian Zhu; Kevin T Mc Henry; William S Lane; Gabriel Fenteany
Journal: Chem Biol Date: 2005-09

5. A new protocol for the consecutive alpha- and beta-activation of propiolates towards electrophiles, involving conjugate addition of tertiary amines and intramolecular silyl migration.

Authors: Yuji Matsuya; Kousuke Hayashi; Hideo Nemoto
Journal: Chemistry Date: 2005-09-05 Impact factor: 5.236

6. Locostatin Disrupts Association of Raf Kinase Inhibitor Protein With Binding Proteins by Modifying a Conserved Histidine Residue in the Ligand-Binding Pocket.

Authors: Anwar B Beshir; Christian E Argueta; Lochana C Menikarachchi; José A Gascón; Gabriel Fenteany
Journal: For Immunopathol Dis Therap Date: 2011

7. Sustained activation of Src-family tyrosine kinases by ischemia: a potential mechanism mediating extracellular signal-regulated kinase cascades in hippocampal dentate gyrus.

Authors: J Guo; H W Wu; G Hu; X Han; W De; Y J Sun
Journal: Neuroscience Date: 2006-09-26 Impact factor: 3.590