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Literature DB >> 21401207

Copper-catalyzed amidation of 2-phenylpyridine with oxygen as the terminal oxidant.

Abstract

The Cu(OAc)(2)-catalyzed, O(2)-mediated amidation of 2-phenylpyridine via C-H bond activation is reported. A variety of nitrogen reagents including sulfonamides, carboxamides, and anilines participate in the reaction in moderate to good yields.

Entities: Chemical

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Year: 2011 PMID： 21401207 DOI： 10.1021/jo200409h

Source DB: PubMed Journal: J Org Chem ISSN： 0022-3263 Impact factor: 4.354

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Cited

18 in total

Review 1. Aerobic copper-catalyzed organic reactions.

Authors: Scott E Allen; Ryan R Walvoord; Rosaura Padilla-Salinas; Marisa C Kozlowski
Journal: Chem Rev Date: 2013-06-20 Impact factor: 60.622

2. Metal-free intermolecular oxidative C-N bond formation via tandem C-H and N-H bond functionalization.

Authors: Abhishek A Kantak; Shathaverdhan Potavathri; Rose A Barham; Kaitlyn M Romano; Brenton DeBoef
Journal: J Am Chem Soc Date: 2011-11-16 Impact factor: 15.419

3. Regioselective C-H bond amination by aminoiodanes.

Authors: Abhishek A Kantak; Louis Marchetti; Brenton DeBoef
Journal: Chem Commun (Camb) Date: 2015-02-28 Impact factor: 6.222

4. Directed amination of non-acidic arene C-H bonds by a copper-silver catalytic system.

Authors: Ly Dieu Tran; James Roane; Olafs Daugulis
Journal: Angew Chem Int Ed Engl Date: 2013-04-24 Impact factor: 15.336

5. Uncovering the mechanism of the Ag(I)/persulfate-catalyzed cross-coupling reaction of arylboronic acids and heteroarenes.

Authors: Niki R Patel; Robert A Flowers
Journal: J Am Chem Soc Date: 2013-03-18 Impact factor: 15.419

10. N-Acyloxyphthalimides as nitrogen radical precursors in the visible light photocatalyzed room temperature C-H amination of arenes and heteroarenes.

Authors: Laura J Allen; Pablo J Cabrera; Melissa Lee; Melanie S Sanford
Journal: J Am Chem Soc Date: 2014-04-04 Impact factor: 15.419

Copper-catalyzed amidation of 2-phenylpyridine with oxygen as the terminal oxidant.

Review 1. Aerobic copper-catalyzed organic reactions.

2. Metal-free intermolecular oxidative C-N bond formation via tandem C-H and N-H bond functionalization.

3. Regioselective C-H bond amination by aminoiodanes.

4. Directed amination of non-acidic arene C-H bonds by a copper-silver catalytic system.

5. Uncovering the mechanism of the Ag(I)/persulfate-catalyzed cross-coupling reaction of arylboronic acids and heteroarenes.

6. A General Method for Aminoquinoline-Directed, Copper-Catalyzed sp(2) C-H Bond Amination.

7. Copper-catalyzed oxidative amination and allylic amination of alkenes.

8. Copper-promoted sulfenylation of sp2 C-H bonds.

9. N-Aminopyridinium Ylide-Directed, Copper-Promoted Amination of sp² C-H Bonds.

10. N-Acyloxyphthalimides as nitrogen radical precursors in the visible light photocatalyzed room temperature C-H amination of arenes and heteroarenes.