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Literature DB >> 21399807

Isolable, gold carbonyl complexes supported by N-heterocyclic carbenes.

Chandrakanta Dash¹, Peter Kroll, Muhammed Yousufuddin, H V Rasika Dias.

Abstract

Cationic gold carbonyl complexes supported by N-heterocyclic carbene ligands, SIDipp and IDipp, have been synthesized. [(SIDipp)Au(CO)][SbF(6)] has a linear, two-coordinate gold center. [(SIDipp)Au(CO)][SbF(6)] and [(IDipp)Au(CO)][SbF(6)] display ̃ν(CO) values at 2197 and 2193 cm(-1), respectively. Computational studies on [(SIMe)Au(CO)](+) indicate the presence of a strong Au(I)-CO bond. © The Royal Society of Chemistry 2011

Entities: Chemical Disease

Year: 2011 PMID： 21399807 DOI： 10.1039/c1cc10622h

Source DB: PubMed Journal: Chem Commun (Camb) ISSN： 1359-7345 Impact factor: 6.222

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Cited

7 in total

1. A hexanuclear gold carbonyl cluster.

Authors: Sonia Martínez-Salvador; Larry R Falvello; Antonio Martín; Babil Menjón
Journal: Chem Sci Date: 2015-06-15 Impact factor: 9.825

2. How π back-donation quantitatively controls the CO stretching response in classical and non-classical metal carbonyl complexes.

Authors: Giovanni Bistoni; Sergio Rampino; Nicola Scafuri; Gianluca Ciancaleoni; Daniele Zuccaccia; Leonardo Belpassi; Francesco Tarantelli
Journal: Chem Sci Date: 2015-10-26 Impact factor: 9.825

3. What can NMR spectroscopy of selenoureas and phosphinidenes teach us about the π-accepting abilities of N-heterocyclic carbenes?

Authors: Sai V C Vummaleti; David J Nelson; Albert Poater; Adrián Gómez-Suárez; David B Cordes; Alexandra M Z Slawin; Steven P Nolan; Luigi Cavallo
Journal: Chem Sci Date: 2015-02-16 Impact factor: 9.825

Isolable, gold carbonyl complexes supported by N-heterocyclic carbenes.

1. A hexanuclear gold carbonyl cluster.

2. How π back-donation quantitatively controls the CO stretching response in classical and non-classical metal carbonyl complexes.

3. What can NMR spectroscopy of selenoureas and phosphinidenes teach us about the π-accepting abilities of N-heterocyclic carbenes?

4. Syntheses and Reactivity of New Zwitterionic Imidazolium Trihydridoborate and Triphenylborate Species.

5. Orbital Decomposition of the Carbon Chemical Shielding Tensor in Gold(I) N-Heterocyclic Carbene Complexes.

6. An element through the looking glass: exploring the Au-C, Au-H and Au-O energy landscape.

7. Gold(III)-CO and gold(III)-CO2 complexes and their role in the water-gas shift reaction.