Literature DB >> 21399775

The structure of gas-phase [Al·nH2O]+: hydrated monovalent aluminium Al+ (H2O)n or hydride-hydroxide HAlOH+ (H2O)(n-1)?

Christian van der Linde1, Martin K Beyer.   

Abstract

Theoretical studies predict that [Al·nH(2)O](+) clusters are present as hydride-hydroxide species HAlOH(+)(H(2)O)(n-1) in gas-phase experiments, energetically favoured by 200 kJ mol(-1) over Al(+)(H(2)O)(n). After collisions with D(2)O, however, no H/D scrambling occurs between H(2)O and D(2)O in clusters with n > 38, indicating that large clusters are present as the higher-energy isomers Al(+)(H(2)O)(n).

Entities:  

Year:  2011        PMID： 21399775     DOI： 10.1039/c1cp00048a

Source DB:  PubMed          Journal:  Phys Chem Chem Phys        ISSN： 1463-9076            Impact factor:   3.676


  7 in total

1.  Photochemistry and spectroscopy of small hydrated magnesium clusters Mg+(H2O)n, n = 1-5.

Authors:  Milan Ončák; Thomas Taxer; Erik Barwa; Christian van der Linde; Martin K Beyer
Journal:  J Chem Phys       Date:  2018-07-28       Impact factor: 3.488

2.  Photochemical Hydrogen Evolution at Metal Centers Probed with Hydrated Aluminium Cations, Al+ (H2 O)n , n=1-10.

Authors:  Jakob Heller; Tobias F Pascher; Christian van der Linde; Milan Ončák; Martin K Beyer
Journal:  Chemistry       Date:  2021-11-05       Impact factor: 5.020

3.  Photochemistry and UV/vis spectroscopy of hydrated vanadium cations, V+(H2O)n, n = 1-41, a model system for photochemical hydrogen evolution.

Authors:  Jakob Heller; Tobias F Pascher; Dominik Muß; Christian van der Linde; Martin K Beyer; Milan Ončák
Journal:  Phys Chem Chem Phys       Date:  2021-10-13       Impact factor: 3.676

4.  Infrared Multiple Photon Dissociation Spectroscopy Confirms Reversible Water Activation in Mn+(H2O)n, n ≤ 8.

Authors:  Jakob Heller; Ethan M Cunningham; Christian van der Linde; Milan Ončák; Martin K Beyer
Journal:  J Phys Chem Lett       Date:  2022-04-07       Impact factor: 6.888

5.  Size-dependent H and H2 formation by infrared multiple photon dissociation spectroscopy of hydrated vanadium cations, V+(H2O)n, n = 3-51.

Authors:  Jakob Heller; Ethan M Cunningham; Jessica C Hartmann; Christian van der Linde; Milan Ončák; Martin K Beyer
Journal:  Phys Chem Chem Phys       Date:  2022-06-22       Impact factor: 3.945

6.  Asymmetric Solvation of the Zinc Dimer Cation Revealed by Infrared Multiple Photon Dissociation Spectroscopy of Zn2+(H2O)n (n = 1-20).

Authors:  Ethan M Cunningham; Thomas Taxer; Jakob Heller; Milan Ončák; Christian van der Linde; Martin K Beyer
Journal:  Int J Mol Sci       Date:  2021-06-02       Impact factor: 5.923

7.  Getting Ready for the Hydrogen Evolution Reaction: The Infrared Spectrum of Hydrated Aluminum Hydride-Hydroxide HAlOH+ (H2 O)n-1 , n=9-14.

Authors:  Jakob Heller; Wai Kit Tang; Ethan M Cunningham; Ephrem G Demissie; Christian van der Linde; Wing Ka Lam; Milan Ončák; Chi-Kit Siu; Martin K Beyer
Journal:  Angew Chem Int Ed Engl       Date:  2021-06-04       Impact factor: 15.336
  7 in total

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