| Literature DB >> 21391584 |
Yanhui Guo1, Hui Wu, Wei Zhou, Xuebin Yu.
Abstract
The strategy of using double-cations to tune the temperature and purity of dehydrogenation of ammine borohydrides is reported. The first double-cation ammine borohydride, Li(2)Al(BH(4))(5)·6NH(3), which forms a novel structure with ordered arrangement of Al(NH(3))(6)(3+) ammine complexes and Li(2)(BH(4))(5)(3-) complex anions, is found to release over 10.0 wt % hydrogen below 120 °C with favorable kinetics and high H-purity (>99%).Entities:
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Year: 2011 PMID： 21391584 DOI： 10.1021/ja1105893
Source DB: PubMed Journal: J Am Chem Soc ISSN： 0002-7863 Impact factor: 15.419