Structural properties and superconductivity of SrFe(2)As(2 - x)P(x) (0.0 ≤ x ≤ 1.0) and CaFe(2)As(2 - y)P(y) (0.0 ≤ y ≤ 0.3).

The SrFe(2)As(2 - x)P(x) (0.0 ≤ x ≤ 1.0) and CaFe(2)As(2 - y)P(y) (0.0 ≤ y ≤ 0.3) materials were prepared by a solid-state reaction method. X-ray diffraction measurements indicate that the single-phase samples can be successfully obtained for SrFe(2)As(2 - x)P(x) (0.0 ≤ x ≤ 0.8) and CaFe(2)As(2 - y)P(y) (0.0 ≤ y ≤ 0.3). Visible contraction of the lattice parameters is determined due to the relatively smaller radius of P ions in comparison with that of As. The spin-density-wave (SDW) instability associated with the tetragonal to orthorhombic phase transition is suppressed noticeably in both systems following the increase in P content. The highest superconducting transitions are observed at about 27 K in SrFe(2)As(1.3)P(0.7) and at about 13 K in CaFe(2)As(1.925)P(0.075), respectively. Structural analysis suggests that lattice contraction could notably affect the superconductivity in these materials.