Directional magnetoelectric effects in MnWO4: magnetic sources of the electric polarization.

The ferroelectric order and magnetic field induced effects observed in the spiral phase of MnWO4 are described theoretically. It is demonstrated explicitly that the Dzyaloshinskii-Moriya antisymmetric interactions contribute to the correlation between spins and electric dipoles in the incommensurate and commensurate ferroelectric phases of magnetic multiferroics. However, other single-site symmetric interactions are shown to be involved in the magnetoelectric process, suggesting the possible existence of an electric polarization originating from purely symmetric effects.