Adilson Y Furuse1, José Mondelli, David C Watts. 1. Master of Science Program in Clinical Dentistry, Department of Dentistry, Positivo University, Rua Professor Pedro Viriato Parigot de Souza, 5300, CEP 81280-330 Curitiba, PR, Brazil. furuseay@yahoo.com.br
Abstract
OBJECTIVES: To evaluate the influence of different tertiary amines on degree of conversion (DC), shrinkage-strain, shrinkage-strain rate, Knoop microhardness, and color and transmittance stabilities of experimental resins containing BisGMA/TEGDMA (3:1wt), 0.25wt% camphorquinone, 1wt% amine (DMAEMA, CEMA, DMPT, DEPT or DABE). Different light-curing protocols were also evaluated. METHODS: DC was evaluated with FTIR-ATR and shrinkage-strain with the bonded-disk method. Shrinkage-strain-rate data were obtained from numerical differentiation of shrinkage-strain data with respect to time. Color stability and transmittance were evaluated after different periods of artificial aging, according to ISO 7491:2000. Results were evaluated with ANOVA, Tukey, and Dunnett's T3 tests (α=0.05). RESULTS: Studied properties were influenced by amines. DC and shrinkage-strain were maximum at the sequence: CQ<DEPT<DMPT≤CEMA≈DABE<DMAEMA. Both DC and shrinkage were also influenced by the curing protocol, with positive correlations between DC and shrinkage-strain and DC and shrinkage-strain rate. Materials generally decreased in L* and increased in b*. The strong exception was the resin containing DMAEMA that did not show dark and yellow shifts. Color varied in the sequence: DMAEMA<DEPT<DMPT<CEMA<DABE. Transmittance varied in the sequence: DEPT≈DABE<DABE≈DMPT≈CEMA<DMPT≈CEMA≈DMAEMA, being more evident at the wavelength of 400nm. No correlations between DC and optical properties were observed. SIGNIFICANCE: The resin containing DMAEMA showed higher DC, shrinkage-strain, shrinkage-strain rate, and microhardness, in addition to better optical properties.
OBJECTIVES: To evaluate the influence of different tertiary amines on degree of conversion (DC), shrinkage-strain, shrinkage-strain rate, Knoop microhardness, and color and transmittance stabilities of experimental resins containing BisGMA/TEGDMA (3:1wt), 0.25wt% camphorquinone, 1wt% amine (DMAEMA, CEMA, DMPT, DEPT or DABE). Different light-curing protocols were also evaluated. METHODS:DC was evaluated with FTIR-ATR and shrinkage-strain with the bonded-disk method. Shrinkage-strain-rate data were obtained from numerical differentiation of shrinkage-strain data with respect to time. Color stability and transmittance were evaluated after different periods of artificial aging, according to ISO 7491:2000. Results were evaluated with ANOVA, Tukey, and Dunnett's T3 tests (α=0.05). RESULTS: Studied properties were influenced by amines. DC and shrinkage-strain were maximum at the sequence: CQ<DEPT<DMPT≤CEMA≈DABE<DMAEMA. Both DC and shrinkage were also influenced by the curing protocol, with positive correlations between DC and shrinkage-strain and DC and shrinkage-strain rate. Materials generally decreased in L* and increased in b*. The strong exception was the resin containing DMAEMA that did not show dark and yellow shifts. Color varied in the sequence: DMAEMA<DEPT<DMPT<CEMA<DABE. Transmittance varied in the sequence: DEPT≈DABE<DABE≈DMPT≈CEMA<DMPT≈CEMA≈DMAEMA, being more evident at the wavelength of 400nm. No correlations between DC and optical properties were observed. SIGNIFICANCE: The resin containing DMAEMA showed higher DC, shrinkage-strain, shrinkage-strain rate, and microhardness, in addition to better optical properties.
Authors: Artem Plyusnin; Jingwei He; Cindy Elschner; Miho Nakamura; Julia Kulkova; Axel Spickenheuer; Christina Scheffler; Lippo V J Lassila; Niko Moritz Journal: Molecules Date: 2021-02-26 Impact factor: 4.411