Literature DB >> 21381768

Catalytic hydrogenation of carboxamides and esters by well-defined Cp*Ru complexes bearing a protic amine ligand.

Masato Ito1, Takashi Ootsuka, Ryo Watari, Akira Shiibashi, Akio Himizu, Takao Ikariya.   

Abstract

A novel catalytic method for the straightforward hydrogenation of carboxamides and esters to primary alcohols has been developed. Chiral modification in the ligand sphere of the well-defined Cp*Ru catalyst molecule opens up a new possibility for the development of an enantioselective hydrogenation of racemic substrates via dynamic kinetic resolution.

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Year:  2011        PMID： 21381768     DOI： 10.1021/ja1117254

Source DB:  PubMed          Journal:  J Am Chem Soc        ISSN： 0002-7863            Impact factor:   15.419


  13 in total

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Authors:  Aaron M Appel; John E Bercaw; Andrew B Bocarsly; Holger Dobbek; Daniel L DuBois; Michel Dupuis; James G Ferry; Etsuko Fujita; Russ Hille; Paul J A Kenis; Cheryl A Kerfeld; Robert H Morris; Charles H F Peden; Archie R Portis; Stephen W Ragsdale; Thomas B Rauchfuss; Joost N H Reek; Lance C Seefeldt; Rudolf K Thauer; Grover L Waldrop
Journal:  Chem Rev       Date:  2013-06-14       Impact factor: 60.622

2.  (Acetonitrile-κN)[2-(diphenylphosphan-yl)ethanamine-κN,P][(1,2,3,4,5-η)-1,2,3,4,5-pentamethylcyclopentadienyl]iron(II) hexafluoridophosphate tetrahydrofuran monosolvate.

Authors:  Kajin Lee; Frank Rominger; Michael Limbach
Journal:  Acta Crystallogr Sect E Struct Rep Online       Date:  2011-07-23

3.  CH2 Linkage Effects on the Reactivity of Bis(aminophosphine)-Ruthenium Complexes for Selective Hydrogenation of Esters into Alcohols.

Authors:  Xiaolong Fang; Mingjun Sun; Jianwei Zheng; Bin Li; Linmin Ye; Xiaoping Wang; Zexing Cao; Hongping Zhu; Youzhu Yuan
Journal:  Sci Rep       Date:  2017-06-21       Impact factor: 4.379

4.  Iridium-catalyzed asymmetric hydrogenation of racemic α-substituted lactones to chiral diols.

Authors:  Xiao-Hui Yang; Hai-Tao Yue; Na Yu; Yi-Pan Li; Jian-Hua Xie; Qi-Lin Zhou
Journal:  Chem Sci       Date:  2016-11-15       Impact factor: 9.825

5.  Efficient and selective hydrogenation of amides to alcohols and amines using a well-defined manganese-PNN pincer complex.

Authors:  Veronica Papa; Jose R Cabrero-Antonino; Elisabetta Alberico; Anke Spanneberg; Kathrin Junge; Henrik Junge; Matthias Beller
Journal:  Chem Sci       Date:  2017-03-08       Impact factor: 9.825

6.  Selective Room-Temperature Hydrogenation of Amides to Amines and Alcohols Catalyzed by a Ruthenium Pincer Complex and Mechanistic Insight.

Authors:  Sayan Kar; Michael Rauch; Amit Kumar; Gregory Leitus; Yehoshoa Ben-David; David Milstein
Journal:  ACS Catal       Date:  2020-04-21       Impact factor: 13.084

7.  Highly chemoselective reduction of amides (primary, secondary, tertiary) to alcohols using SmI2/amine/H2O under mild conditions.

Authors:  Michal Szostak; Malcolm Spain; Andrew J Eberhart; David J Procter
Journal:  J Am Chem Soc       Date:  2014-01-31       Impact factor: 15.419

8.  Multifaceted catalytic hydrogenation of amides via diverse activation of a sterically confined bipyridine-ruthenium framework.

Authors:  Takashi Miura; Masayuki Naruto; Katsuaki Toda; Taiki Shimomura; Susumu Saito
Journal:  Sci Rep       Date:  2017-05-16       Impact factor: 4.379

9.  Towards a general ruthenium-catalyzed hydrogenation of secondary and tertiary amides to amines.

Authors:  Jose R Cabrero-Antonino; Elisabetta Alberico; Kathrin Junge; Henrik Junge; Matthias Beller
Journal:  Chem Sci       Date:  2016-02-09       Impact factor: 9.825

Review 10.  Homogeneous and heterogeneous catalytic reduction of amides and related compounds using molecular hydrogen.

Authors:  Jose R Cabrero-Antonino; Rosa Adam; Veronica Papa; Matthias Beller
Journal:  Nat Commun       Date:  2020-08-04       Impact factor: 14.919
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