Literature DB >> 21380454

Copper-catalyzed trifluoromethylation of aryl boronic acids using a CF3+ reagent.

Jun Xu1, Dong-Fen Luo, Bin Xiao, Zhao-Jing Liu, Tian-Jun Gong, Yao Fu, Lei Liu.   

Abstract

A copper-catalyzed process for trifluoromethylation of aryl, heteroaryl, and vinyl boronic acids has been developed. The reaction is conducted under mild conditions and shows tolerance to moisture and a variety of functional groups.

Entities:  

Year:  2011        PMID： 21380454     DOI： 10.1039/c1cc10359h

Source DB:  PubMed          Journal:  Chem Commun (Camb)        ISSN： 1359-7345            Impact factor:   6.222


  20 in total

1.  Silver-mediated trifluoromethylation of arenes using TMSCF3.

Authors:  Yingda Ye; Shin Hee Lee; Melanie S Sanford
Journal:  Org Lett       Date:  2011-09-20       Impact factor: 6.005

2.  Merging visible-light photocatalysis and transition-metal catalysis in the copper-catalyzed trifluoromethylation of boronic acids with CF3I.

Authors:  Yingda Ye; Melanie S Sanford
Journal:  J Am Chem Soc       Date:  2012-05-24       Impact factor: 15.419

3.  Investigations into Transition Metal Catalyzed Arene Trifluoromethylation Reactions.

Authors:  Yingda Ye; Melanie S Sanford
Journal:  Synlett       Date:  2012-09-01       Impact factor: 2.454

4.  Julia-Kocienski Approach to Trifluoromethyl-Substituted Alkenes1.

Authors:  Deborah O Ayeni; Samir K Mandal; Barbara Zajc
Journal:  Tetrahedron Lett       Date:  2013-11-06       Impact factor: 2.415

Review 5.  Visible light photoredox catalysis with transition metal complexes: applications in organic synthesis.

Authors:  Christopher K Prier; Danica A Rankic; David W C MacMillan
Journal:  Chem Rev       Date:  2013-03-19       Impact factor: 60.622

6.  Copper-mediated radical trifluoromethylation of unsaturated potassium organotrifluoroborates.

Authors:  Marc Presset; Daniel Oehlrich; Frederik Rombouts; Gary A Molander
Journal:  J Org Chem       Date:  2013-11-19       Impact factor: 4.354

7.  Trifluoromethylation of arenes and heteroarenes by means of photoredox catalysis.

Authors:  David A Nagib; David W C MacMillan
Journal:  Nature       Date:  2011-12-08       Impact factor: 49.962

8.  A general strategy for the perfluoroalkylation of arenes and arylbromides by using arylboronate esters and [(phen)CuR(F)].

Authors:  Nichole D Litvinas; Patrick S Fier; John F Hartwig
Journal:  Angew Chem Int Ed Engl       Date:  2011-11-14       Impact factor: 15.336

Review 9.  High-valent organometallic copper and palladium in catalysis.

Authors:  Amanda J Hickman; Melanie S Sanford
Journal:  Nature       Date:  2012-04-11       Impact factor: 49.962

10.  Practical method for the Cu-mediated trifluoromethylation of arylboronic acids with CF3 radicals derived from NaSO2CF3 and tert-butyl hydroperoxide (TBHP).

Authors:  Yingda Ye; Stefan A Künzi; Melanie S Sanford
Journal:  Org Lett       Date:  2012-09-17       Impact factor: 6.005
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