Literature DB >> 21380452

The bis(hydrogenheptaphosphide)iron(II) dianion: a Zintl ion analogue of ferrocene?

Caroline M Knapp1, Joseph S Large, Nicholas H Rees, Jose M Goicoechea.   

Abstract

Reaction of K(3)P(7), FeCl(2), [NH(4)][B(C(6)H(5))(4)] and 2,2,2-crypt yielded the unprecedented cluster dianion [Fe(HP(7))(2)](2-). This species was characterized by single crystal X-ray diffraction, multielement NMR spectroscopy and electrospray mass-spectrometry. DFT calculations on the dianion were also conducted.

Entities:  

Year:  2011        PMID: 21380452     DOI: 10.1039/c1cc10236b

Source DB:  PubMed          Journal:  Chem Commun (Camb)        ISSN: 1359-7345            Impact factor:   6.222


  1 in total

1.  Haptotropism in a Nickel Complex with a Neutral, π-Bridging cyclo-P4 Ligand Analogous to Cyclobutadiene.

Authors:  Chris Gendy; Juuso Valjus; Heikki M Tuononen; Roland Roesler
Journal:  Angew Chem Int Ed Engl       Date:  2022-03-09       Impact factor: 16.823

  1 in total

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