Literature DB >> 21375344

Aqueous-phase deactivation and intramolecular [2 + 2 + 2] cycloaddition of oxanorbornadiene esters.

Alexander A Kislukhin1, Cody J Higginson, M G Finn.   

Abstract

Both inter- and intramolecular degradation pathways were identified for the aqueous phase deactivation of oxanorbornadiene (OND) electrophiles, and propargylic OND esters were found to undergo facile intramolecular [2 + 2 + 2] homo-Diels-Alder cycloaddition in polar media.

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Year:  2011        PMID： 21375344      PMCID： PMC3101023          DOI： 10.1021/ol103153f

Source DB:  PubMed          Journal:  Org Lett        ISSN： 1523-7052            Impact factor:   6.005


  11 in total

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2.  Degradable conjugates from oxanorbornadiene reagents.

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6.  Strain-Release Heteroatom Functionalization: Development, Scope, and Stereospecificity.

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Journal:  J Am Chem Soc       Date:  2017-02-20       Impact factor: 15.419
  6 in total

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