| Literature DB >> 21370859 |
Feng-Ji Ma1, Shu-Xia Liu, Chun-Yan Sun, Da-Dong Liang, Guo-Jian Ren, Feng Wei, Ya-Guang Chen, Zhong-Min Su.
Abstract
A sodalite-type porous metal-organic framework with polyoxometalate templates, H(3)[(Cu(4)Cl)(3)(BTC)(8)](2)[PW(12)O(40)]·(C(4)H(12)N)(6)·3H(2)O (NENU-11; BTC = 1,3,5-benzenetricarboxylate), was obtained by a hydrothermal reaction. As a reasonable candidate for eliminating nerve gas, NENU-11 displays good adsorption behavior for dimethyl methylphosphonate (15.5 molecules per formula unit). In virtue of the catalytic activity of polyoxometalate guests, this nerve gas mimic could be facilely decomposed by a hydrolysis reaction.Entities:
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Year: 2011 PMID: 21370859 DOI: 10.1021/ja109659k
Source DB: PubMed Journal: J Am Chem Soc ISSN: 0002-7863 Impact factor: 15.419