Literature DB >> 21359325

First proton triggered C-ON bond homolysis in alkoxyamines.

Paul Brémond1, Sylvain R A Marque.   

Abstract

Rate constants k(d) of the C-ON bond homolysis in a new type of alkoxyamines (initiator/controller for Nitroxide Mediated Polymerization) carrying alkyl fragments capable of protonation were measured. A 20-fold increase was reported for the protonated alkoxyamine compared to the non-protonated homologue as predicted (Chem. Soc. Rev., 2011).

Entities:  

Year:  2011        PMID: 21359325     DOI: 10.1039/c0cc05637e

Source DB:  PubMed          Journal:  Chem Commun (Camb)        ISSN: 1359-7345            Impact factor:   6.222


  4 in total

1.  Trityl-based alkoxyamines as NMP controllers and spin-labels.

Authors:  Gérard Audran; Elena G Bagryanskaya; Paul Brémond; Mariya V Edeleva; Sylvain R A Marque; Dmitriy A Parkhomenko; Olga Yu Rogozhnikova; Victor M Tormyshev; Evgeny V Tretyakov; Dmitry V Trukhin; Svetlana I Zhivetyeva
Journal:  Polym Chem       Date:  2016-10-12       Impact factor: 5.582

2.  NMR and EPR Study of Homolysis of Diastereomeric Alkoxyamines.

Authors:  Sergey Cherkasov; Dmitriy Parkhomenko; Alexander Genaev; Georgii Salnikov; Mariya Edeleva; Denis Morozov; Tatyana Rybalova; Igor Kirilyuk; Sylvain R A Marque; Elena Bagryanskaya
Journal:  Molecules       Date:  2020-11-01       Impact factor: 4.411

3.  How intramolecular coordination bonding (ICB) controls the homolysis of the C-ON bond in alkoxyamines.

Authors:  Gérard Audran; Elena Bagryanskaya; Irina Bagryanskaya; Mariya Edeleva; Jean-Patrick Joly; Sylvain R A Marque; Anna Iurchenkova; Polina Kaletina; Sergey Cherkasov; Tung To Hai; Evgeny Tretyakov; Svetlana Zhivetyeva
Journal:  RSC Adv       Date:  2019-08-16       Impact factor: 3.361

4.  Stability of SG1 nitroxide towards unprotected sugar and lithium salts: a preamble to cellulose modification by nitroxide-mediated graft polymerization.

Authors:  Guillaume Moreira; Laurence Charles; Mohamed Major; Florence Vacandio; Yohann Guillaneuf; Catherine Lefay; Didier Gigmes
Journal:  Beilstein J Org Chem       Date:  2013-08-06       Impact factor: 2.883

  4 in total

北京卡尤迪生物科技股份有限公司 © 2022-2023.