Literature DB >> 21355624

Palladium-catalyzed oxidative sp2 C-H bond acylation with alcohols.

Fuhong Xiao1, Qi Shuai, Feng Zhao, Olivier Baslé, Guojun Deng, Chao-Jun Li.   

Abstract

An efficient method was developed for the direct acylation of arene sp(2) C-H bonds with alcohols using palladium chloride as a catalyst and peroxide as the oxidant. The alcohols were oxidized to their corresponding aldehydes in situ and efficiently coupled with 2-arylpyridines to give aryl ketones in chlorobenzene.

Entities:  

Year:  2011        PMID： 21355624     DOI： 10.1021/ol200017a

Source DB:  PubMed          Journal:  Org Lett        ISSN： 1523-7052            Impact factor:   6.005


  4 in total

1.  Rhodium(iii)-catalyzed synthesis of phthalides by cascade addition and cyclization of benzimidates with aldehydes.

Authors:  Yajing Lian; Robert G Bergman; Jonathan A Ellman
Journal:  Chem Sci       Date:  2012-08-02       Impact factor: 9.825

2.  Cobalt(III)-catalyzed synthesis of indazoles and furans by C-H bond functionalization/addition/cyclization cascades.

Authors:  Joshua R Hummel; Jonathan A Ellman
Journal:  J Am Chem Soc       Date:  2014-12-24       Impact factor: 15.419

3.  H-bonded reusable template assisted para-selective ketonisation using soft electrophilic vinyl ethers.

Authors:  Arun Maji; Amit Dahiya; Gang Lu; Trisha Bhattacharya; Massimo Brochetta; Giuseppe Zanoni; Peng Liu; Debabrata Maiti
Journal:  Nat Commun       Date:  2018-09-04       Impact factor: 14.919

4.  Late-Stage C-H Acylation of Tyrosine-Containing Oligopeptides with Alcohols.

Authors:  Iñaki Urruzuno; Paula Andrade-Sampedro; Arkaitz Correa
Journal:  Org Lett       Date:  2021-09-03       Impact factor: 6.005
  4 in total

北京卡尤迪生物科技股份有限公司 © 2022-2023.