| Literature DB >> 21355562 |
Takashi Okubo1, Hiroyasu Kuwamoto, Kyung Ho Kim, Shinya Hayami, Akihito Yamano, Motoo Shiro, Masahiko Maekawa, Takayoshi Kuroda-Sowa.
Abstract
The reaction of Cu(Hm-dtc)(2), Br(2), and CuBr(2) yielded a new mixed-valence octanuclear Cu(I)/Cu(II)/Cu(III) cluster, encapsulating a Br anion in the center of the cluster cage. The octanuclear cluster units form a 1D assemblage, which induces intervalence charge-transfer transitions from Cu(II) ions to Cu(III) ions between the clusters.Entities:
Year: 2011 PMID： 21355562 DOI： 10.1021/ic101794u
Source DB: PubMed Journal: Inorg Chem ISSN： 0020-1669 Impact factor: 5.165