| Literature DB >> 21351769 |
Rafael Huacuja1, Daniel J Graham, Claudia M Fafard, Chun-Hsing Chen, Bruce M Foxman, David E Herbert, Glen Alliger, Christine M Thomas, Oleg V Ozerov.
Abstract
The Pd(I)-Pd(I) dimer [((F)PNP)Pd-](2) reacts with O(2) upon exposure to light to produce either the superoxide ((F)PNP)PdO(2) or the peroxide [((F)PNP)PdO-](2), which exist in equilibrium with free O(2). Both complexes contain square-planar Pd(II) centers. The unpaired electron density in ((F)PNP)PdO(2) is localized on the superoxide ligand.Entities:
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Year: 2011 PMID： 21351769 DOI： 10.1021/ja200346a
Source DB: PubMed Journal: J Am Chem Soc ISSN： 0002-7863 Impact factor: 15.419