Literature DB >> 21350743

Functionalization of the corrole ring: the role of isocorrole intermediates.

Luca Tortora1, Sara Nardis, Frank R Fronczek, Kevin M Smith, Roberto Paolesse.   

Abstract

Bromination of 3-nitro-5,10,15-triarylcorrole selectively provides two regioisomers, depending on the reaction pathway. An isocorrole species is the key intermediate to drive the reaction towards the 2-Br-17-nitro regioisomer.

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Year:  2011        PMID: 21350743      PMCID: PMC3070944          DOI: 10.1039/c0cc05837h

Source DB:  PubMed          Journal:  Chem Commun (Camb)        ISSN: 1359-7345            Impact factor:   6.222


  13 in total

1.  Selective substitution of corroles: nitration, hydroformylation, and chlorosulfonation.

Authors:  Irena Saltsman; Atif Mahammed; Israel Goldberg; Elena Tkachenko; Mark Botoshansky; Zeev Gross
Journal:  J Am Chem Soc       Date:  2002-06-26       Impact factor: 15.419

2.  Synthesis and characterization of free-base, copper, and nickel isocorroles.

Authors:  Giuseppe Pomarico; Xiao Xiao; Sara Nardis; Roberto Paolesse; Frank R Fronczek; Kevin M Smith; Yuanyuan Fang; Zhongping Ou; Karl M Kadish
Journal:  Inorg Chem       Date:  2010-06-21       Impact factor: 5.165

3.  Synthesis and atructure of [meso-triarylcorrolato]silver(III).

Authors:  Christian Brückner; Cheri A Barta; Raymond P Briñas; Jeanette A Krause Bauer
Journal:  Inorg Chem       Date:  2003-03-10       Impact factor: 5.165

4.  Functionalization of corroles: the nitration reaction.

Authors:  Manuela Stefanelli; Marco Mastroianni; Sara Nardis; Silvia Licoccia; Frank R Fronczek; Kevin M Smith; Weihua Zhu; Zhongping Ou; Karl M Kadish; Roberto Paolesse
Journal:  Inorg Chem       Date:  2007-11-07       Impact factor: 5.165

5.  Manganese as a template: a new synthesis of corrole.

Authors:  M Bröring; C Hell
Journal:  Chem Commun (Camb)       Date:  2001-11-21       Impact factor: 6.222

6.  Metallocorroles as cytoprotective agents against oxidative and nitrative stress in cellular models of neurodegeneration.

Authors:  Lana Kupershmidt; Zoya Okun; Tamar Amit; Silvia Mandel; Irena Saltsman; Atif Mahammed; Orit Bar-Am; Zeev Gross; Moussa B H Youdim
Journal:  J Neurochem       Date:  2010-01-24       Impact factor: 5.372

7.  Tumor detection and elimination by a targeted gallium corrole.

Authors:  Hasmik Agadjanian; Jun Ma; Altan Rentsendorj; Vinod Valluripalli; Jae Youn Hwang; Atif Mahammed; Daniel L Farkas; Harry B Gray; Zeev Gross; Lali K Medina-Kauwe
Journal:  Proc Natl Acad Sci U S A       Date:  2009-04-02       Impact factor: 11.205

8.  Reductive demetallation of Cu-corroles--a new protective strategy towards functional free-base corroles.

Authors:  Thien Huynh Ngo; Wim Van Rossom; Wim Dehaen; Wouter Maes
Journal:  Org Biomol Chem       Date:  2008-12-16       Impact factor: 3.876

9.  Demetalation of silver(III) corrolates.

Authors:  Manuela Stefanelli; Jing Shen; Weihua Zhu; Marco Mastroianni; Federica Mandoj; Sara Nardis; Zhongping Ou; Karl M Kadish; Frank R Fronczek; Kevin M Smith; Roberto Paolesse
Journal:  Inorg Chem       Date:  2009-07-20       Impact factor: 5.165

10.  Aura of corroles.

Authors:  Iris Aviv-Harel; Zeev Gross
Journal:  Chemistry       Date:  2009-08-24       Impact factor: 5.236

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  6 in total

1.  β-Nitro-5,10,15-tritolylcorroles.

Authors:  Manuela Stefanelli; Giuseppe Pomarico; Luca Tortora; Sara Nardis; Frank R Fronczek; Gregory T McCandless; Kevin M Smith; Machima Manowong; Yuanyuan Fang; Ping Chen; Karl M Kadish; Angela Rosa; Giampaolo Ricciardi; Roberto Paolesse
Journal:  Inorg Chem       Date:  2012-06-05       Impact factor: 5.165

2.  Synthetic protocols for the nitration of corroles.

Authors:  Giuseppe Pomarico; Frank R Fronczek; Sara Nardis; Kevin M Smith; Roberto Paolesse
Journal:  J Porphyr Phthalocyanines       Date:  2011-07-15       Impact factor: 1.811

3.  Corrole and nucleophilic aromatic substitution are not incompatible: a novel route to 2,3-difunctionalized copper corrolates.

Authors:  M Stefanelli; F Mandoj; S Nardis; M Raggio; F R Fronczek; G T McCandless; K M Smith; R Paolesse
Journal:  Org Biomol Chem       Date:  2015-05-19       Impact factor: 3.876

4.  Amination reaction on copper and germanium β-nitrocorrolates.

Authors:  Manuela Stefanelli; Federica Mandoj; Marco Mastroianni; Sara Nardis; Pruthviray Mohite; Frank R Fronczek; Kevin M Smith; Karl M Kadish; Xiao Xiao; Zhongping Ou; Ping Chen; Roberto Paolesse
Journal:  Inorg Chem       Date:  2011-07-28       Impact factor: 5.165

5.  The Selective Monobromination of a Highly Sterically Encumbered Corrole: Structural and Spectroscopic Properties of Fe(Cl)(2-Bromo-5,10,15-tris(triphenyl)phenyl corrole).

Authors:  Jessica G Alvarado; Daniel C Cummins; Andrada Diaconescu; Maxime A Siegler; David P Goldberg
Journal:  J Porphyr Phthalocyanines       Date:  2021       Impact factor: 1.914

6.  β-Octabromo- and β-Octakis(trifluoromethyl)isocorroles: New Sterically Constrained Macrocyclic Ligands.

Authors:  Kolle E Thomas; Christine M Beavers; Kevin J Gagnon; Abhik Ghosh
Journal:  ChemistryOpen       Date:  2017-05-26       Impact factor: 2.911

  6 in total

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