Literature DB >> 21344098

The impact of the alkali cation on the mechanism of the electro-oxidation of ethylene glycol on Pt.

Elton Sitta1, Bruno C Batista, Hamilton Varela.   

Abstract

By means of in situ IR spectroscopy we investigate the effect of dissolved alkali cations on the electro-oxidation of ethylene glycol on platinum in alkaline media. The results revealed that the increase in the oxidation currents (Li(+) < Na(+) < K(+)) is reflected in the increase in the ratio between carbonate and oxalate produced.

Entities:  

Year:  2011        PMID： 21344098     DOI： 10.1039/c0cc05353h

Source DB:  PubMed          Journal:  Chem Commun (Camb)        ISSN： 1359-7345            Impact factor:   6.222


  5 in total

1.  The electro-oxidation of ethylene glycol on platinum over a wide pH range: oscillations and temperature effects.

Authors:  Elton Sitta; Raphael Nagao; Hamilton Varela
Journal:  PLoS One       Date:  2013-09-18       Impact factor: 3.240

2.  Carbon-neutral energy cycles using alcohols.

Authors:  Takashi Fukushima; Sho Kitano; Shinichi Hata; Miho Yamauchi
Journal:  Sci Technol Adv Mater       Date:  2018-02-15       Impact factor: 8.090

3.  Spectroelectrochemical studies on the effect of cations in the alkaline glycerol oxidation reaction over carbon nanotube-supported Pd nanoparticles.

Authors:  Dennis Hiltrop; Steffen Cychy; Karina Elumeeva; Wolfgang Schuhmann; Martin Muhler
Journal:  Beilstein J Org Chem       Date:  2018-06-12       Impact factor: 2.883

4.  Hydrogen production by electrochemical reaction using ethylene glycol with terephthalic acid.

Authors:  Se-Hyun Kim; Sang-Won Woo; Chan-Soo Kim; Sung-Eun Lee; Tae-Oh Kim
Journal:  RSC Adv       Date:  2021-01-07       Impact factor: 3.361

5.  Experimental assessment of the sensitiveness of an electrochemical oscillator towards chemical perturbations.

Authors:  Graziela C A Ferreira; Bruno C Batista; Hamilton Varela
Journal:  PLoS One       Date:  2012-11-21       Impact factor: 3.240
  5 in total

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