| Literature DB >> 21341786 |
Jeremy M Lenhardt1, James W Ogle, Mitchell T Ong, Robert Choe, Todd J Martinez, Stephen L Craig.
Abstract
Tension along a polymer chain traps neighboring s-trans/s-trans-1,3-diradicals from the mechanically induced ring opening of gem-difluorocyclopropanes (gDFCs). The diradicals correspond to the transition states of the force-free thermal isomerization reactions of gDFCs, and the tension trapping allows a new disproportionation reaction between two simultaneously trapped diradicals to take place.Entities:
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Year: 2011 PMID： 21341786 DOI： 10.1021/ja107645c
Source DB: PubMed Journal: J Am Chem Soc ISSN： 0002-7863 Impact factor: 15.419