| Literature DB >> 21341757 |
Alessandro Donoli1, Vanessa Marcuzzo, Alessandro Moretto, Claudio Toniolo, Roberta Cardena, Annalisa Bisello, Saverio Santi.
Abstract
Two series of 3(10)-helical peptides of different lengths and rigidity, based on the strongly foldameric α-aminoisobutyric acid and containing a terminal ferrocenyl unit, have been synthesized. Oxidation-state sensitive spectroscopic tags of helical peptides, the N-H groups, allowed mapping of the charge delocalization triggered by oxidation of the terminal ferrocenyl moiety and were monitored by IR spectroelectrochemistry.Entities:
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Year: 2011 PMID： 21341757 DOI： 10.1021/ol102864s
Source DB: PubMed Journal: Org Lett ISSN： 1523-7052 Impact factor: 6.005