Literature DB >> 21341722

CpRu-catalyzed O-H insertion and condensation reactions of α-diazocarbonyl compounds.

Martina Austeri1, Diane Rix, Walid Zeghida, Jérôme Lacour.   

Abstract

[CpRu(CH(3)CN)(3)][PF(6)] and diimine ligands catalyze together the decomposition of α-diazocarbonyl compounds leading to O-H insertion and condensation reactions. In comparison with Rh(II) and Cu(I) complexes, the CpRu catalysts produce rapid and often more selective reactions. Promising enantioselectivities are obtained in dioxole syntheses.

Entities:  

Year:  2011        PMID： 21341722     DOI： 10.1021/ol2000815

Source DB:  PubMed          Journal:  Org Lett        ISSN： 1523-7052            Impact factor:   6.005


  8 in total

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Review 8.  From reactive carbenes to chiral polyether macrocycles in two steps - synthesis and applications made easy?

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  8 in total

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