Literature DB >> 21341714

S(N)Ar reactions of nitro-(pentafluorosulfanyl)benzenes to generate SF5 aryl ethers and sulfides.

Petr Beier1, Tereza Pastýříková, Norbert Vida, George Iakobson.   

Abstract

Nucleophilic aromatic substitution of the nitro group of para- and meta-nitro-(pentafluorosulfanyl)benzene with alkoxides and thiolates generates a range of substituted 4- and 3-(pentafluorosulfanyl)benzenes in a single-step reaction.

Entities:  

Year:  2011        PMID： 21341714     DOI： 10.1021/ol2001478

Source DB:  PubMed          Journal:  Org Lett        ISSN： 1523-7052            Impact factor:   6.005


  7 in total

1.  Microbial biotransformation of aryl sulfanylpentafluorides.

Authors:  Emma Kavanagh; Michael Winn; Cliona Nic Gabhann; Neil K O'Connor; Petr Beier; Cormac D Murphy
Journal:  Environ Sci Pollut Res Int       Date:  2013-07-20       Impact factor: 4.223

2.  Highly selective synthesis of (E)-alkenyl-(pentafluorosulfanyl)benzenes through Horner-Wadsworth-Emmons reaction.

Authors:  George Iakobson; Petr Beier
Journal:  Beilstein J Org Chem       Date:  2012-07-25       Impact factor: 2.883

3.  Pyridine-promoted dediazoniation of aryldiazonium tetrafluoroborates: Application to the synthesis of SF5-substituted phenylboronic esters and iodobenzenes.

Authors:  George Iakobson; Junyi Du; Alexandra M Z Slawin; Petr Beier
Journal:  Beilstein J Org Chem       Date:  2015-08-26       Impact factor: 2.883

4.  Synthesis of Phthalocyanines with a Pentafluorosulfanyl Substituent at Peripheral Positions.

Authors:  Norihito Iida; Kenta Tanaka; Etsuko Tokunaga; Satoru Mori; Norimichi Saito; Norio Shibata
Journal:  ChemistryOpen       Date:  2015-07-24       Impact factor: 2.911

5.  Synthesis of SF5-containing benzisoxazoles, quinolines, and quinazolines by the Davis reaction of nitro-(pentafluorosulfanyl)benzenes.

Authors:  Petr Beier; Tereza Pastýříková
Journal:  Beilstein J Org Chem       Date:  2013-02-21       Impact factor: 2.883

6.  Synthesis and nucleophilic aromatic substitution of 3-fluoro-5-nitro-1-(pentafluorosulfanyl)benzene.

Authors:  Javier Ajenjo; Martin Greenhall; Camillo Zarantonello; Petr Beier
Journal:  Beilstein J Org Chem       Date:  2016-02-03       Impact factor: 2.883

7.  Synthesis of pentafluorosulfanyl (SF5) containing aromatic amino acids.

Authors:  Lucas Grigolato; William D G Brittain; Alex S Hudson; Maria M Czyzewska; Steven L Cobb
Journal:  J Fluor Chem       Date:  2018-08       Impact factor: 2.050
  7 in total

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