Literature DB >> 21331388

14N and 45Sc NMR study of trimetallic nitride cluster (M3N)6+ dynamics inside a icosahedral C80 cage.

Wujun Fu1, Xuelei Wang, Hugo Azuremendi, Jianyuan Zhang, Harry C Dorn.   

Abstract

The dynamics of the trimetallic nitride (M(3)N)(6+) (M = Sc, Y and Lu) clusters in the I(h)-(C(80))(6-) cage have been studied by (14)N and (45)Sc nuclear magnetic resonance. These NMR studies suggest that the motional barrier of (M(3)N)(6+) is related to the cluster size and increases in the series (Sc, Y, and Lu).

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Year:  2011        PMID: 21331388     DOI: 10.1039/c0cc03893h

Source DB:  PubMed          Journal:  Chem Commun (Camb)        ISSN: 1359-7345            Impact factor:   6.222


  3 in total

1.  Electrostatic Interaction across a Single-Layer Carbon Shell.

Authors:  R Stania; A P Seitsonen; D Kunhardt; B Büchner; A A Popov; M Muntwiler; T Greber
Journal:  J Phys Chem Lett       Date:  2018-06-18       Impact factor: 6.475

2.  Magnetic anisotropy of endohedral lanthanide ions: paramagnetic NMR study of MSc2N@C80-Ih with M running through the whole 4f row.

Authors:  Y Zhang; D Krylov; M Rosenkranz; S Schiemenz; A A Popov
Journal:  Chem Sci       Date:  2015-01-28       Impact factor: 9.825

3.  Endohedral metal-nitride cluster ordering in metallofullerene-NiII(OEP) complexes and crystals: a theoretical study.

Authors:  Vasilii Dubrovin; Li-Hua Gan; Bernd Büchner; Alexey A Popov; Stanislav M Avdoshenko
Journal:  Phys Chem Chem Phys       Date:  2019-04-17       Impact factor: 3.676

  3 in total

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