Literature DB >> 21323384

Pd-catalyzed desulfitative Heck coupling with dioxygen as the terminal oxidant.

Xianya Zhou1, Jiaying Luo, Jing Liu, Shengming Peng, Guo-Jun Deng.   

Abstract

A Pd-catalyzed desulfitative Heck-type reaction of aromatic sulfinic acid sodium salts with various olefins is developed with O(2) as the terminal oxidant under mild conditions. The presence of phosphane ligand DPEphos in anisole can significantly enhance the reaction selectivity.

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Year:  2011        PMID： 21323384     DOI： 10.1021/ol200101x

Source DB:  PubMed          Journal:  Org Lett        ISSN： 1523-7052            Impact factor:   6.005


  6 in total

1.  Aryliodine (III) Diacetates as Substrates for Pd-Ag Catalyzed Arylation of Alkenes.

Authors:  Nikolai M Evdokimov; Alexander Kornienko; Igor V Magedov
Journal:  Tetrahedron Lett       Date:  2011-08-17       Impact factor: 2.415

2.  Bond-Forming and -Breaking Reactions at Sulfur(IV): Sulfoxides, Sulfonium Salts, Sulfur Ylides, and Sulfinate Salts.

Authors:  Daniel Kaiser; Immo Klose; Rik Oost; James Neuhaus; Nuno Maulide
Journal:  Chem Rev       Date:  2019-06-25       Impact factor: 60.622

3.  Mechanistic Studies of the Palladium-Catalyzed Desulfinative Cross-Coupling of Aryl Bromides and (Hetero)Aryl Sulfinate Salts.

Authors:  Antoine de Gombert; Alasdair I McKay; Christopher J Davis; Katherine M Wheelhouse; Michael C Willis
Journal:  J Am Chem Soc       Date:  2020-02-07       Impact factor: 15.419

4.  Palladium-catalyzed Tsuji-Trost-type reaction of benzofuran-2-ylmethyl acetates with nucleophiles.

Authors:  Antonio Arcadi; Giancarlo Fabrizi; Andrea Fochetti; Francesca Ghirga; Antonella Goggiamani; Antonia Iazzetti; Federico Marrone; Giulia Mazzoccanti; Andrea Serraiocco
Journal:  RSC Adv       Date:  2021-01-04       Impact factor: 3.361

5.  Iodine-promoted stereoselective amidosulfenylation of electron-deficient alkynes.

Authors:  Fuhong Xiao; Dahan Wang; Shanshan Yuan; Huawen Huang; Guo-Jun Deng
Journal:  RSC Adv       Date:  2018-06-27       Impact factor: 4.036

6.  DABSO-based, three-component, one-pot sulfone synthesis.

Authors:  Alex S Deeming; Claire J Russell; Alan J Hennessy; Michael C Willis
Journal:  Org Lett       Date:  2013-12-05       Impact factor: 6.005
  6 in total

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