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Literature DB >> 21322115

Facile preparation of homo- and hetero-dimetallic complexes with a 4-phosphino-substituted NHC ligand. Toward the design of multifunctional catalysts.

Daniel Mendoza-Espinosa¹, Bruno Donnadieu, Guy Bertrand.

Abstract

A series of bipan class="Chemical">metaln>lic complexes have been synthesized that are supported by a n>an class="Chemical">4-phosphino-substituted NHC ligand. The use of this stable ligand reduces the number of synthetic steps and allows for a wide range of metal combinations to be introduced into the complexes.

Entities: Chemical Disease Gene Species

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Year: 2011 PMID： 21322115 PMCID： PMC3118523 DOI： 10.1002/asia.201000856

Source DB: PubMed Journal: Chem Asian J ISSN： 1861-471X

37 in total

1. Stable Carbenes.

Authors: Didier Bourissou; Olivier Guerret; François P. Gabbaï; Guy Bertrand
Journal: Chem Rev Date: 2000-01-12 Impact factor: 60.622

2. Synthesis of 4- and 4,5-functionalized imidazol-2-ylidenes from a single 4,5-unsubstituted imidazol-2-ylidene.

Authors: Daniel Mendoza-Espinosa; Bruno Donnadieu; Guy Bertrand
Journal: J Am Chem Soc Date: 2010-06-02 Impact factor: 15.419

3. Base-promoted tautomerization of imidazole ligands to N-heterocyclic carbenes and subsequent transmetalation reaction.

Authors: Javier Ruiz; Bernabé F Perandones
Journal: J Am Chem Soc Date: 2007-07-04 Impact factor: 15.419

4. Triazolediylidenes: a versatile class of ligands for the preparation of discrete molecules of homo- and hetero-binuclear complexes for improved catalytic applications.

Authors: Elena Mas-Marzá; José A Mata; Eduardo Peris
Journal: Angew Chem Int Ed Engl Date: 2007 Impact factor: 15.336

5. Beyond conventional N-heterocyclic carbenes: abnormal, remote, and other classes of NHC ligands with reduced heteroatom stabilization.

Authors: Oliver Schuster; Liangru Yang; Helgard G Raubenheimer; Martin Albrecht
Journal: Chem Rev Date: 2009-08 Impact factor: 60.622

6. Grubbs' ruthenium-carbenes beyond the metathesis reaction: less conventional non-metathetic utility.

Authors: Benito Alcaide; Pedro Almendros; Amparo Luna
Journal: Chem Rev Date: 2009-08 Impact factor: 60.622

7. Versatile new C(3)-symmetric tripodal tetraphosphine ligands; structural flexibility to stabilize Cu(I) and Rh(I) species and tune their reactivity.

Authors: Jeroen Wassenaar; Maxime A Siegler; Anthony L Spek; Bas de Bruin; Joost N H Reek; Jarl Ivar van der Vlugt
Journal: Inorg Chem Date: 2010-07-19 Impact factor: 5.165

Facile preparation of homo- and hetero-dimetallic complexes with a 4-phosphino-substituted NHC ligand. Toward the design of multifunctional catalysts.

1. Stable Carbenes.

2. Synthesis of 4- and 4,5-functionalized imidazol-2-ylidenes from a single 4,5-unsubstituted imidazol-2-ylidene.

3. Base-promoted tautomerization of imidazole ligands to N-heterocyclic carbenes and subsequent transmetalation reaction.

4. Triazolediylidenes: a versatile class of ligands for the preparation of discrete molecules of homo- and hetero-binuclear complexes for improved catalytic applications.

5. Beyond conventional N-heterocyclic carbenes: abnormal, remote, and other classes of NHC ligands with reduced heteroatom stabilization.

6. Grubbs' ruthenium-carbenes beyond the metathesis reaction: less conventional non-metathetic utility.

7. Versatile new C(3)-symmetric tripodal tetraphosphine ligands; structural flexibility to stabilize Cu(I) and Rh(I) species and tune their reactivity.

8. Abnormal binding in a carbene complex formed from an imidazolium salt and a metal hydride complex.

9. C4-bound imidazolylidenes: from curiosities to high-impact carbene ligands.

10. Well-defined Ir/Pd complexes with a triazolyl-diylidene bridge as catalysts for multiple tandem reactions.

1. Extending N-heterocyclic carbene ligands into the third dimension: a new type of hybrid phosphazane/NHC system.

Review 2. Functionalised N-Heterocyclic Carbene Ligands in Bimetallic Architectures.