Literature DB >> 21321708

Hydrosilylation of epoxides catalyzed by a cationic η1-silane iridium(III) complex.

Sehoon Park1, Maurice Brookhart.   

Abstract

Cationic silane complex 2, catalyzes the hydrosilylation of epoxides and cyclic ethers to give the silyl-protected alcohols, regioselectively. A mechanistic study shows that the epoxide undergoes isomerization to the ketone, followed by hydrosilylation.

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Year:  2011        PMID： 21321708     DOI： 10.1039/c0cc05714b

Source DB:  PubMed          Journal:  Chem Commun (Camb)        ISSN： 1359-7345            Impact factor:   6.222


  5 in total

1.  Silylation reactions on nanoporous gold via homolytic Si-H activation of silanes.

Authors:  Hongbo Li; Huifang Guo; Zhiwen Li; Cai Wu; Jing Li; Chunliang Zhao; Shuangxi Guo; Yi Ding; Wei He; Yadong Li
Journal:  Chem Sci       Date:  2018-04-30       Impact factor: 9.825

2.  Insight into catalytic reduction of CO2 to methane with silanes using Brookhart's cationic Ir(iii) pincer complex.

Authors:  Shaoqin Fang; Hongcai Chen; Haiyan Wei
Journal:  RSC Adv       Date:  2018-03-02       Impact factor: 4.036

Review 3.  Activation of Si-H and B-H bonds by Lewis acidic transition metals and p-block elements: same, but different.

Authors:  Pablo Ríos; Amor Rodríguez; Salvador Conejero
Journal:  Chem Sci       Date:  2022-06-06       Impact factor: 9.969

4.  Primary Alcohols via Nickel Pentacarboxycyclopentadienyl Diamide Catalyzed Hydrosilylation of Terminal Epoxides.

Authors:  Keri A Steiniger; Tristan H Lambert
Journal:  Org Lett       Date:  2021-10-06       Impact factor: 6.072

5.  Markovnikov alcohols via epoxide hydroboration by molecular alkali metal catalysts.

Authors:  Guoqi Zhang; Haisu Zeng; Shengping Zheng; Michelle C Neary; Pavel A Dub
Journal:  iScience       Date:  2022-09-12
  5 in total

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