Literature DB >> 21318071

Ag(x)VOPO(4): A Demonstration of the Dependence of Battery-Related Electrochemical Properties of Silver Vanadium Phosphorous Oxides on Ag / V Ratios.

Young Jin Kim1, Chia-Ying Lee, Amy C Marschilok, Kenneth J Takeuchi, Esther S Takeuchi.   

Abstract

As a part of our on-going study on silver vanadium phosphorous oxides (Ag(x)V(y)O(z)PO(4)), we report here the first study of the electrochemical reduction of a low Ag/V ratio silver vanadium phosphorous oxide, Ag(0.48)VOPO(4)·1.9H(2)O. Reminiscent of Ag(2)VO(2)PO(4) reduction, in-situ formation of silver metal nanoparticles along with an associated increase in conductivity were observed after reduction of Ag(0.48)VOPO(4)·1.9H(2)O with 0.37 electron equivalents. However, in contrast to our lithium / Ag(2)VO(2)PO(4) cells, our lithium / Ag(0.48)VOPO(4)·1.9H(2)O cells displayed an even higher voltage on discharge and a characteristic multi-plateau voltage profile, where vanadium reduction was the first reduction step.

Entities:  

Year:  2011        PMID: 21318071      PMCID: PMC3035415          DOI: 10.1016/j.jpowsour.2010.11.144

Source DB:  PubMed          Journal:  J Power Sources        ISSN: 0378-7753            Impact factor:   9.127


  3 in total

1.  Electrochemical Reduction of Silver Vanadium Phosphorous Oxide, Ag(2)VO(2)PO(4): Silver Metal Deposition and Associated Increase in Electrical Conductivity.

Authors:  Amy C Marschilok; Eric S Kozarsky; Kevin Tanzil; Shali Zhu; Kenneth J Takeuchi; Esther S Takeuchi
Journal:  J Power Sources       Date:  2010-10-01       Impact factor: 9.127

2.  New Metal-Intercalated Layered Vanadyl Phosphates, M(x)()VOPO(4).yH(2)O (M = Ag, Cu, Zn).

Authors:  P. Ayyappan; A. Ramanan; C. C. Torardi
Journal:  Inorg Chem       Date:  1998-07-13       Impact factor: 5.165

3.  Electrochemical reduction of silver vanadium phosphorous oxide, Ag(2)VO(2)PO(4): the formation of electrically conductive metallic silver nanoparticles.

Authors:  Esther S Takeuchi; Amy C Marschilok; Kevin Tanzil; Eric S Kozarsky; Shali Zhu; Kenneth J Takeuchi
Journal:  Chem Mater       Date:  2009-10-27       Impact factor: 9.811

  3 in total
  6 in total

1.  Batteries used to Power Implantable Biomedical Devices.

Authors:  David C Bock; Amy C Marschilok; Kenneth J Takeuchi; Esther S Takeuchi
Journal:  Electrochim Acta       Date:  2012-12-01       Impact factor: 6.901

2.  Secondary Battery Science: At the Confluence of Electrochemistry and Materials Engineering.

Authors:  Esther S Takeuchi; Amy C Marschilok; Kenneth J Takeuchi
Journal:  Electrochemistry (Tokyo)       Date:  2012-10       Impact factor: 1.381

3.  A Kinetics and Equilibrium Study of Vanadium Dissolution from Vanadium Oxides and Phosphates in Battery Electrolytes: Possible Impacts on ICD Battery Performance.

Authors:  David C Bock; Amy C Marschilok; Kenneth J Takeuchi; Esther S Takeuchi
Journal:  J Power Sources       Date:  2013-06-01       Impact factor: 9.127

4.  Silver Vanadium Diphosphate Ag2VP2O8: Electrochemistry and Characterization of Reduced Material providing Mechanistic Insights.

Authors:  Esther S Takeuchi; Chia-Ying Lee; Po-Jen Chen; Melissa C Menard; Amy C Marschilok; Kenneth J Takeuchi
Journal:  J Solid State Chem       Date:  2013-04       Impact factor: 3.498

5.  ZnFe2O4-C/LiFePO4-CNT: A Novel High-Power Lithium-Ion Battery with Excellent Cycling Performance.

Authors:  Alberto Varzi; Dominic Bresser; Jan von Zamory; Franziska Müller; Stefano Passerini
Journal:  Adv Energy Mater       Date:  2014-03-24       Impact factor: 29.368

Review 6.  Power Approaches for Implantable Medical Devices.

Authors:  Achraf Ben Amar; Ammar B Kouki; Hung Cao
Journal:  Sensors (Basel)       Date:  2015-11-13       Impact factor: 3.576

  6 in total

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