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Literature DB >> 21309571

Supramolecular AA-BB-type linear polymers with relatively high molecular weights via the self-assembly of bis(m-phenylene)-32-crown-10 cryptands and a bisparaquat derivative.

Zhenbin Niu¹, Feihe Huang, Harry W Gibson.

Abstract

Two novel bis(m-phenylene)-32-crown-10-based cryptands, one bearing covalent linkages and the other metal-complex linkages, were designed and prepared. By self-assembly of these biscryptands, which can be viewed as AA monomers, and a bisparaquat, which can be viewed as a BB monomer, AA-BB-type linear supramolecular polymers with relatively high molecular weights were successfully prepared.

Entities: Chemical

Year: 2011 PMID： 21309571 DOI： 10.1021/ja110384v

Source DB: PubMed Journal: J Am Chem Soc ISSN： 0002-7863 Impact factor: 15.419

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Cited

8 in total

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Journal: Proc Natl Acad Sci U S A Date: 2014-06-02 Impact factor: 11.205

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Authors: Nora L Löw; Egor V Dzyuba; Boris Brusilowskij; Lena Kaufmann; Elisa Franzmann; Wolfgang Maison; Emily Brandt; Daniel Aicher; Arno Wiehe; Christoph A Schalley
Journal: Beilstein J Org Chem Date: 2012-02-09 Impact factor: 2.883

5. Multistimuli Sensitive Behavior of Novel Bodipy-Involved Pillar[5]arene-Based Fluorescent [2]Rotaxane and Its Supramolecular Gel.

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Supramolecular AA-BB-type linear polymers with relatively high molecular weights via the self-assembly of bis(m-phenylene)-32-crown-10 cryptands and a bisparaquat derivative.

1. Supramolecular polymers with tunable topologies via hierarchical coordination-driven self-assembly and hydrogen bonding interfaces.

2. Pillar[5]arene-based amphiphilic supramolecular brush copolymer: fabrication, controllable self-assembly and application in self-imaging targeted drug delivery.

3. Photoinduced transformations of stiff-stilbene-based discrete metallacycles to metallosupramolecular polymers.

4. Synthesis of multivalent host and guest molecules for the construction of multithreaded diamide pseudorotaxanes.

5. Multistimuli Sensitive Behavior of Novel Bodipy-Involved Pillar[5]arene-Based Fluorescent [2]Rotaxane and Its Supramolecular Gel.

6. Construction of pillar[4]arene[1]quinone-1,10-dibromodecane pseudorotaxanes in solution and in the solid state.

7. The Construction of Cucurbit[7]uril-Based Supramolecular Nanomedicine for Glioma Therapy.

8. Synthesis and investigation of new cyclic molecules using the stilbene scaffold.