| Literature DB >> 21286636 |
Rita Beel1, Stefanie Kobialka, Martin L Schmidt, Marianne Engeser.
Abstract
SOMO catalysis has lately obtained large interest as a new and powerful version of enantioselective organocatalysis which includes radical steps initiated by a one-electron oxidation. The intermediate enamine radical cation has been postulated, but has not been observed directly so far. This communication now reports the direct detection of this key intermediate.Entities:
Year: 2011 PMID： 21286636 DOI： 10.1039/c0cc05347c
Source DB: PubMed Journal: Chem Commun (Camb) ISSN： 1359-7345 Impact factor: 6.222